2007
DOI: 10.1021/ma070386z
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Metal-Free Ring-Opening Polymerization of Glycidyl Phenyl Ether by Tetrabutylammonium Fluoride

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Cited by 30 publications
(38 citation statements)
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“…Numerous interests have been devoted to the ring‐opening polymerization of epoxide monomers to form polymeric and oligomeric polyether polyols, which are used for the production of detergents, nonionic surfactants, washing agents, and polyurethane production process 1, 2…”
Section: Introductionmentioning
confidence: 99%
“…Numerous interests have been devoted to the ring‐opening polymerization of epoxide monomers to form polymeric and oligomeric polyether polyols, which are used for the production of detergents, nonionic surfactants, washing agents, and polyurethane production process 1, 2…”
Section: Introductionmentioning
confidence: 99%
“…S2) measurements was found to be 36, 35, and 40 nm, respectively. Upon intrachain ROP of the GMA units, [29][30][31][32][33] a complete disappearance of the 1 H NMR bands corresponding to glycidylic protons was observed (Fig. 1C).…”
mentioning
confidence: 99%
“…It should also be noted that the polymerization of GPE is accompanied by frequent side reactions (i.e., chain transfer and termination reactions) that limit the increase in the molecular weights of poly(GPE). [13][14][15][16] We have recently developed a controlled anionic ring opening polymerization of GPE initiated with metal-free tetra-nbutylammonium fluoride (Bu 4 NF), due to a strong CAF bond formed at the initiating chain end of polymer 17,18 ; however, Bu 4 NF is hard to use because of its high hygroscopic property. Furthermore, the initiating chain end of the resulting polymer cannot be converted to other functional groups because of the strong CAF bond.…”
mentioning
confidence: 99%