Metal hydrazide complexes

Polymeric and mixed ligand complex of cobalt(II) and 4-hydroxybenzhydrazide: Crystal structure and vibrational spectroscopy

“…In the metal coordination, the 4hbah acts as a bidentate ligand which employs carbonyl oxygen and a terminal nitrogen atom of the hydrazide, contributing in the five-membered chelate ring. Such coordination mode is typical for hydrazides [23]. The organic ligand, together with two water molecules and two SO 2À 4 groups occupy six positions of Co(II) coordination polyhedron.…”

Green approach to synthesize novel thiosemicarbazide complexes, characterization; DNA-methyl green assay and in-silico studies against DNA polymerase

“…Thiosemicarbazone compounds of copper and nickel were created, investigated, and found to have different antiviral properties [ 13 ]. By constructing various thiosemicarbazieds from monobasic or dibasic forms, several metal ion complexes have been produced [ 14 ]. New Ni(II) and Co(II) complexes with hydrazide ligands displayed anticancer activity [ 15 ].…”

Relative Solution Equilibria and Chemical Speciation study of Divalent Manganese and Cobalt Ternary complexes with Azelaic acid dihydrazide (AZDH), L-Proline & L-Lysine

“…The development of an eight-membered ring is required for the ω-NH2 group to participate, which is sterically unfavourable. However, in biological systems, the importance of the lysine side chain ω-NH2 group in metal ion binding is well established [12][13][14][15][16]. Because of the strong basicity of the ω-NH2 group, a number of protonated metal complexes occur in solution.…”