The energy barrier heights between an ultra-smooth amorphous metal electrode, ZrCuAlNi, and several atomic layer deposited (ALD) insulators are measured using internal photoemission (IPE) spectroscopy. ZrCuAlNiinsulator barriers are characterized within metal-insulator-metal (MIM) stacks with Al top contacts and results are compared with the Al/insulator barrier heights. The measured barrier heights at the ZrCuAlNi interface are found to be 3.3, 3.2, 3.0, and 2.2 eV for SiO 2 , Al 2 O 3 , HfO 2 , and ZrO 2 , respectively. This barrier height trend is consistent with the electron affinity of the respective oxides. However, barriers for SiO 2 and Al 2 O 3 are smaller than that ideally expected based on the reported vacuum work function of ZrCuAlNi, indicating a smaller ZrCuAlNi effective work function in these device structures. The measured Al barrier height results confirm previous reports of a negative dipole at the Al-ALD insulator interface.