Metal-Ion Type Effect on the Crystal Structure and Optical Properties of 2,2′-bipyridine Complexes of Pb(II) and Cd(II)

Najafi, Ezzatollah; Amini, Mostafa M.; Yousefi, Pegah; Ng, Seik Weng

doi:10.1007/s10904-018-0898-4

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2021

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“…When the lone pair is inert in a nine-coordinate environment, the geometry is largely TRPS-9 (Lobo et al, 2019;Mahmoudi et al, 2019), SAPRS-9 (Deng et al, 2013;Farina et al, 2013;Hayati et al, 2018;Imran et al, 2015;Kowalik et al, 2017;Lobo et al, 2019;Mahmoudi et al, 2019;Morsali & Mahjoub, 2004;Najafi et al, 2018;Song et al, 2014;Zhao et al, 2007) and CUS-9 (Farina et al, 2013;Né meth et al, 2015;Yang et al, 2019) (Table S6). For one selected example, the authors (Morsali & Mahjoub, 2004) argue for a void around the ninecoordinate Pb II atom so that the lone pair should be active.…”

Section: Resultsmentioning

confidence: 99%

Ψ-Polyhedral symbols for coordination geometries of lead(II) with a stereochemically active lone pair

2021

Acta Crystallogr C

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Because an IUCr/IUPAC-designated set of letters/numbers identifies the configuration of the atoms linked to the PbII atom in its coordination compounds, a Ψ prefix before such as a polyhedral symbol provides useful information when its lone pair is stereochemically active. Such notation is especially relevant when the metal atom is connected to eight or more atoms regardless of whether the lone pair is active or inert. The polyhedral symbols for the crystal structures in some 50 articles published after 2000 are reported here as the original studies did not expressly identify coordination geometries.

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Section: Resultsmentioning

confidence: 99%

Metal-Ion Type Effect on the Crystal Structure and Optical Properties of 2,2′-bipyridine Complexes of Pb(II) and Cd(II)

Cited by 1 publication

References 40 publications

Ψ-Polyhedral symbols for coordination geometries of lead(II) with a stereochemically active lone pair

Ψ-Polyhedral symbols for coordination geometries of lead(II) with a stereochemically active lone pair

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