Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4

Cui, Wen-Gang; Zhang, Guoying; Hu, Tong‐Liang; Bu, Xian‐He

doi:10.1016/j.ccr.2019.02.001

Cited by 338 publications

(136 citation statements)

References 347 publications

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“…Due to their unique physicochemical properties and regulated functional structure, metal-organic frameworks (MOFs) materials have widely been used in the fields of CO 2 conversion, [111] separation, [112] and capture [113] . Li et al first identified the possibility of using MOFs as cathode catalysts in Li-CO 2 batteries.…”

Section: Metal-organic Complex Catalystsmentioning

confidence: 99%

“…[39] Li-CO 2 cells demonstrated with the Ni-NG catalyst a superior discharge capacity (17 625 mAh g À1 ). Density functional theory (DFT) calculation results indicated that the (111) and (200) highly exposed crystal faces could facilitate the combination of CO 2 with Li þ to form Li 2 CO 3 products. [39] In a different way, Qiao et al prepared a Ni/graphene (Ni nanoparticles on reduced graphene) catalyst by combining thermal shock synthesis with a 3D printing technique ( Figure 10a).…”

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confidence: 99%

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Recent Advances in Lithium–Carbon Dioxide Batteries

Manthiram

2020

Small Structures

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Toward global sustainable development, lithium-carbon dioxide (Li-CO 2) batteries not only serve as an energy-storage technology but also represent a CO 2 capture system. Since the beginning of their research in this decade, Li-CO 2 batteries have attracted growing attention. However, Li-CO 2 batteries are still in their infancy and are facing many scientific and technological challenges. From a fundamental perspective, the reaction mechanism of CO 2 cathode is not yet clear enough. Technologically, the high overpotential, low power density, poor rate capability, and limited cycle life impede the development of Li-CO 2 batteries for practical applications. Herein, the recent research progress in Li-CO 2 batteries in terms of reaction mechanisms, cathode catalyst design, electrolyte management, and anode protection are first summarized. In light of the state-of-the-art research advances, future perspectives and research directions are then put forward, aiming to provide insightful information for the development of practical Li-CO 2 batteries.

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Section: Metal-organic Complex Catalystsmentioning

confidence: 99%

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confidence: 99%

Recent Advances in Lithium–Carbon Dioxide Batteries

Manthiram

2020

Small Structures

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“…By varying the combination of the selected OL/SBU, as well as the synthesis conditions, different crystalline porous networks can be obtained [63,64]. These solids possess a series of interesting features such as extremely high specific surface area, large pore volume, ordered three-dimensional (3D) structure and elevated adsorption properties, making them interesting candidates for applications in materials science [65][66][67][68]. Some examples of MOF systems, together with their specific surface areas, are reported in Figure 2 All the abovementioned characteristics, together with the possibility of fine-tuning the metal organic architecture, allow explaining the use of MOF structures in fields ranging from gas adsorption and storage to drug delivery, magnetism, and luminescence, among others.…”

Section: Metal-organic Framework (Mof)-based Catalystsmentioning

confidence: 99%

Hybrid Catalysts for CO2 Conversion into Cyclic Carbonates

2019

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The conversion of carbon dioxide into valuable chemicals such as cyclic carbonates is an appealing topic for the scientific community due to the possibility of valorizing waste into an inexpensive, available, nontoxic, and renewable carbon feedstock. In this regard, last-generation heterogeneous catalysts are of great interest owing to their high catalytic activity, robustness, and easy recovery and recycling. In the present review, recent advances on CO 2 cycloaddition to epoxide mediated by hybrid catalysts through organometallic or organo-catalytic species supported onto silica-, nanocarbon-, and metal-organic framework (MOF)-based heterogeneous materials, are highlighted and discussed.

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“…[9][10][11][12][13][14][15][16] Over the past 20 years, MOFs generation has been one of the important branches in the area of heterogeneous catalysis, owing to their tailored pore size and diverse catalytic centers. 5,10,[17][18][19][20][21][22] Especially, the design of acid-base bifunctional MOF catalysts is an attractive but difficult work, and the formation of most catalytic sites of the existing MOF catalysts has focused on the use of open metal sites as Lewis acid, and basic organic groups of ligands as Lewis bases. 3,[23][24][25][26][27][28][29][30][31][32][33] However, the application of Brønsted acidbase MOF catalysts for tandem or cascade reactions has rarely been reported due to the sluggish Brønsted acid/ base chemistry in MOFs.…”

Section: Introductionmentioning

confidence: 99%

Designing a Bifunctional Brønsted Acid–Base Heterogeneous Catalyst Through Precise Installation of Ligands on Metal–Organic Frameworks

Xue

et al. 2020

CCS Chem.

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A Brønsted acid-base bifunctional metal-organic framework (MOF) catalyst, PCN-700-AB [A = Brønsted acid site, TPDC-(COOH) 2 [(1,1′∶4′,1″terphenyl)-2,2″,4,4″-tetracarboxylic acid] and B = Brønsted basic site, BDC-NH 2 ], was designed precisely and synthesized successfully through sequential installation of Brønsted acid and base functionalities in a crystalline zirconium (Zr)-MOF. The installation underwent single-crystal-to-singlecrystal transformation throughout the process; hence, the structure of the bifunctional catalyst could be characterized accurately via single-crystal X-ray crystallography. The bifunctional MOF catalyst obtained exhibited excellent acid-base catalytic activity for a cascade of one-pot deacetalization-Knoevenagel condensation reaction. The work presented here could be considered as a promising solution to incorporate multifunctional components readily, especially the hostile aspects, into one MOF structure.

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Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4

Cited by 338 publications

References 347 publications

Recent Advances in Lithium–Carbon Dioxide Batteries

Recent Advances in Lithium–Carbon Dioxide Batteries

Hybrid Catalysts for CO2 Conversion into Cyclic Carbonates

Designing a Bifunctional Brønsted Acid–Base Heterogeneous Catalyst Through Precise Installation of Ligands on Metal–Organic Frameworks

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