Metal organic framework-based nanostructure materials: applications for non-lithium ion battery electrodes

Wang, Jinghan; Kirlikovali, Kent O.; Kim, Soo Young; Kim, Dong Wan; Varma, Rajender S.; Jang, Ho Won; Farha, Omar K.; Shokouhimehr, Mohammadreza

doi:10.1039/d1ce01737c

Cited by 22 publications

(7 citation statements)

References 144 publications

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“…Electrochemical energy storage technologies employing sustainable rechargeable batteries are indispensable for the efficient integration of renewable energies into large-scale electric grids. − Albeit lithium-ion batteries (LIBs) possess high energy density, their sustainability is strongly impeded by the safety issues associated with flammable organic electrolytes, potential lithium crisis, and the supply shortages of other crucial elements. Metallic anode-based aqueous batteries, which can offer higher theoretical capacity and better safety, are therefore emerging as an alternative energy storage technology. , Among the metal electrodes, featured by the highest theoretical volumetric capacity, as well as the low cost and highest abundance in the earth’s crust, the sustainable aqueous aluminum metal batteries (AMBs) are considered to be the next generation of batteries for energy conversion and storage systems. − …”

Section: Introductionmentioning

confidence: 99%

Reversible Al Metal Anodes Enabled by Amorphization for Aqueous Aluminum Batteries

et al. 2022

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Aqueous aluminum metal batteries (AMBs) are regarded as one of the most sustainable energy storage systems among post-lithium-ion candidates, which is attributable to their highest theoretical volumetric capacity, inherent safe operation, and low cost. Yet, the development of aqueous AMBs is plagued by the incapable aluminum plating in an aqueous solution and severe parasitic reactions, which results in the limited discharge voltage, thus making the development of aqueous AMBs unsuccessful so far. Here, we demonstrate that amorphization is an effective strategy to tackle these critical issues of a metallic Al anode by shifting the reduction potential for Al deposition. The amorphous aluminum (a-Al) interfacial layer is triggered by an in situ lithium-ion alloying/dealloying process on a metallic Al substrate with low strength. Unveiled by experimental and theoretical investigations, the amorphous structure greatly lowers the Al nucleation energy barrier, which forces the Al deposition competitive to the electron-stealing hydrogen evolution reaction (HER). Simultaneously, the inhibited HER mitigates the passivation, promoting interfacial ion transfer kinetics and enabling steady aluminum plating/stripping for 800 h in the symmetric cell. The resultant multiple full cells using Al@a-Al anodes deliver approximately a 0.6 V increase in the discharge voltage plateau compared to that of bare Al-based cells, which far outperform all reported aqueous AMBs. In both symmetric cells and full cells, the excellent electrochemical performances are achieved in a noncorrosive, low-cost, and fluorine-free Al 2 (SO 4 ) 3 electrolyte, which is ecofriendly and can be easily adapted for sustainable large-scale applications. This work brings an intriguing picture of the design of metallic anodes for reversible and high-voltage AMBs.

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Section: Introductionmentioning

confidence: 99%

Reversible Al Metal Anodes Enabled by Amorphization for Aqueous Aluminum Batteries

et al. 2022

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“…Metal‐organic frameworks (MOFs) have gained much attention as a result of two particularly impressive features: numerous micropores and a large specific surface area [127,128] . However, MOFs are mixed with other materials to create more excellent MOF‐derived functional materials, which overcome the limits of weak conductivity and low stability of pure MOF‐based materials.…”

Section: Recent Exploration Of Electrolyte Anode and Cathode Material...mentioning

confidence: 99%

“…MOF‐derived functional materials not only inherit the porosity and surface area of the original MOF crystals, but they may also have improved characteristics due to the synergistic impact between functional units. More importantly, the MOF‐derived functional materials have the structural properties of pristine MOFs under the right transformation circumstances [127–131] . Metal‐organic framework (MOF, HKUST‐1) precursors have been synthesized using a simple hydrothermal approach in the literature, and CuTe@C composites are effectively formed after carbonization/tellurization treatment.…”

Section: Recent Exploration Of Electrolyte Anode and Cathode Material...mentioning

confidence: 99%

High Performance and Long‐cycle Life Rechargeable Aluminum Ion Battery: Recent Progress, Perspectives and Challenges

Nayem

Ahmad

Shah

et al. 2022

The Chemical Record

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The rising energy crisis and environmental concerns caused by fossil fuels have accelerated the deployment of renewable and sustainable energy sources and storage systems. As a result of immense progress in the field, cost-effective, high-performance, and long-life rechargeable batteries are imperative to meet the current and future demands for sustainable energy sources. Currently, lithium-ion batteries are widely used, but limited lithium (Li) resources have caused price spikes, threatening progress toward cleaner energy sources. Therefore, post-Li, batteries that utilize highly abundant materials leading to cost-effective energy storage solutions while offering desirable performance characteristics are urgently needed. Aluminum-ion battery (AIB) is an attractive concept that uses highly abundant aluminum while offering a high theoretical gravimetric and volumetric capacity of 2980 mAh g À 1 and 8046 mAh cm À 3 , respectively. As a result, intensified efforts have been made in recent years to utilize numerous electrolytes, anodes, and cathode materials to improve the electrochemical performance of AIBs, and potentially create high-performance, low-cost, and safe energy storage devices. Herein, recent progress in the electrolyte, anode, and cathode active materials and their utilization in AIBs and their related characteristics are summarized. Finally, the main challenges facing AIBs along with future directions are highlighted.

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“…Moreover, MOFs with pyridine and dicarboxylate ligands show various singlet and triplet energy states to generate fine optical signals. − The advantages of such MOFs are as follows: (i) rigid frameworks even after interaction with other guest metal ions, (ii) π-electrons that can interact with the incoming metal ions, (iii) a large pore volume that can accommodate heavy-metal ions easily without disturbing the overall network, and (iv) high energy storage and conversion. − Recently, MOF sensors with pyridine dicarboxylate ligands and lanthanide/d-block metal ions have been reported for environmental and biochemical applications. − Therefore, the design of MOF sensors to detect heavy-metal ions is an interesting area of research …”

Section: Introductionmentioning

confidence: 99%

Water- and pH-Stable Methylthio-Containing Metal–Organic Frameworks as Luminescent Sensors for Metal-Ion Detection

Mohan

Tao

Kumar

et al. 2022

Crystal Growth & Design

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Currently, metal–organic frameworks (MOFs) with thiol functionalities are used as advanced robust materials to solve the problems of pollution and damage caused by metal ions in water. Herein, we report a framework assembled by reacting cadmium nitrate with a new ligand, 4-methylthiopyridine-2,6-dicarboxylic acid, which possesses methylthio and carboxyl functional groups. The resultant MOFs exhibit 5-c net, fnb-type, uninodal net topology with {33·4·64·72} point symbols. The thiol-functionalized MOF features good thermal, water, and pH stabilities and luminescence emission at different temperatures. The methylthio-containing cadmium MOF (Cd-MOF) selectively detects the heavy-metal ions Cu2+, Hg2+, and Pb2+ in water by luminescence quenching, with low limits of detection (LODs) of 22.60 × 10–7, 11.07 × 10–6, and 9.58 × 10–6 M, respectively. The highly selective response and performance of the Cd-MOF probe toward Cu2+, Hg2+, and Pb2+ ions were determined by investigating the effects of other interfering ions and different pH values, and the reusability performance was evaluated.

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Metal organic framework-based nanostructure materials: applications for non-lithium ion battery electrodes

Abstract: Non-lithium ion (e.g., Al3+, Ca2+, K+, Mg2+, Na+, and Zn2+) batteries have emerged as a promising platform for next-generation energy storage systems.

Cited by 22 publications

References 144 publications

Reversible Al Metal Anodes Enabled by Amorphization for Aqueous Aluminum Batteries

Reversible Al Metal Anodes Enabled by Amorphization for Aqueous Aluminum Batteries

High Performance and Long‐cycle Life Rechargeable Aluminum Ion Battery: Recent Progress, Perspectives and Challenges

Water- and pH-Stable Methylthio-Containing Metal–Organic Frameworks as Luminescent Sensors for Metal-Ion Detection

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