2020
DOI: 10.1016/j.electacta.2020.136640
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Metal-organic framework MIL-101(Fe)–NH2 as an efficient host for sulphur storage in long-cycle Li–S batteries

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Cited by 53 publications
(24 citation statements)
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“…54,55 Improving the electrochemical behaviour of the sulphur cathode can be achieved with various carbon materials with high conductivity, tunability, and porosity. 56 As such, several types of materials have been used to improve cyclic stability: functionalized carbon, 57,58 metal oxides/sulphides/ nitrides, [59][60][61] covalent-organic frameworks 62 and metal-organic frameworks, [63][64][65][66][67][68][69] all of the mentioned materials have a high affinity for polar polysulphides.…”
Section: Introductionmentioning
confidence: 99%
“…54,55 Improving the electrochemical behaviour of the sulphur cathode can be achieved with various carbon materials with high conductivity, tunability, and porosity. 56 As such, several types of materials have been used to improve cyclic stability: functionalized carbon, 57,58 metal oxides/sulphides/ nitrides, [59][60][61] covalent-organic frameworks 62 and metal-organic frameworks, [63][64][65][66][67][68][69] all of the mentioned materials have a high affinity for polar polysulphides.…”
Section: Introductionmentioning
confidence: 99%
“…Meanwhile, the intensity of integral of peak separation clearly reveals the main valence state of Fe in NH 2 -MIL-101(Fe) is divalent, which is agreement with four-coordination structure of NH 2 -MIL-101(Fe). ( Zhang et al., 2016 ; Capková et al., 2020 ).
Figure 4 (a) XPS full spectra and (b) high-resolution Fe 2p for NH 2 -MIL-101(Fe).
…”
Section: Resultsmentioning
confidence: 99%
“…Capková et al prepared MIL-101(Fe)-NH 2 , which successfully achieved sulfur capture and encapsulation. 129 As the cathode for lithium–sulfur batteries, it displayed highly stable cycle performance, high efficiency (retaining 67.6% of the initial capacity at 0.5 C after 200 cycles and the coulombic efficiency of 95%). Similarly, Benítez et al synthesized MIL-88A by a sustainable, simple and short-time method with the assistance of ultrasound.…”
Section: Fe-based Mofs For Battery Applicationsmentioning
confidence: 99%