Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials

Effect of Transition Metal Cations on Assembly of Highly Ordered 2D Multiporphyrin Arrays on Liquid and Solid Substrates

“…Первые исследования МОК были направлены на получение ма-териалов с предельно высокими площадью поверхно-сти и объемом пор для хранения водорода и метана. [1][2][3][4] Эти «классические» области использования МОК как микропористых структур были стремительно распро-странены на другие сферы потенциального примене-ния, простирающиеся далеко за пределы сорбционных материалов. Исследование МОК-структур подтвердило перспективы их применения в качестве основы для получения нового класса материалов, обладающих существенными преимуществами в широком ряде об-ластей: хранение, транспортировка и разделение газов, катализ, фотоника, электроника, сенсорика и многие другие.…”

The Diphosphorus Complex [Cp2Mo2(CO)4(η2‐P2)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers

“…Rapid development has been achieved in the construction of discrete and extended molecular architectures by self‐assembly processes 1. Such derivatives can be classified as “inorganic‐organic” supramolecular complexes as they are usually obtained from two‐component reactions involving the coordination of organic ligands bearing N, O, or S donor atoms to Lewis‐acidic inorganic metal cations.…”

“…Such derivatives can be classified as “inorganic‐organic” supramolecular complexes as they are usually obtained from two‐component reactions involving the coordination of organic ligands bearing N, O, or S donor atoms to Lewis‐acidic inorganic metal cations. [1h], 2 Due to the lack of P donating connectors and the usual use of simple transition‐metal cations, our group established an alternative approach by utilising organometallic polyphosphorus (P n ) ligand complexes with flexible coordination modes as connectors between metal ions. By using this novel method, it was possible to synthesize one‐ and two‐dimensional coordination polymers,3 vast fullerene‐like supramolecular spherical aggregates,4 and organometallic nanosized capsules 5.…”

On-surface self-organization of a robust metal–organic cluster based on copper(i) with chloride and organosulphur ligands

“…In this context, to combine organic molecules with metal entities is particularly useful. 4,5 On the other hand, the bottom-up approach for forming on-surface nanostructures by direct sublimation of their building blocks under ultra-high vacuum conditions has been shown as an excellent approach to this goal. 6 However, this experimental approach presents a limitation coming from the stability that it is required for the molecule to allow sublimation without structural damage.…”

“…Recently, we have reported on the synthesis and characterization of a robust metal-organic cluster [Cu 4 (m 3 -Cl) 4 (m-pym 2 S 2 ) 4 ] (pym 2 S 2 = dipyrimidinedisulfide) (1) showing interesting physical and chemical properties. Previous studies indicate a remarkable stability of this molecule and its capability to change its structure to produce a 2D-coordination polymer, [Cu(m-pym 2 S 2 )(m-Cl)] n ÁnS (S = H 2 O or EtOH), when exposed to water or ethanol.…”