Metal–organic frameworks and their derivatives as electrode materials for Li-ion batteries: a mini review

Chen, Yueying; Du, Wenqing; Dou, Bingxin; Hu, Lei; Zeb, Akif; Lin, Xiaoming

doi:10.1039/d2ce00167e

Cited by 21 publications

(5 citation statements)

References 95 publications

(111 reference statements)

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“…LIBs are frequently used in portable electronic devices and electric vehicles thanks to their extended cycling lifespan, wide voltage window, environmental friendliness, and high power density. [94] MOFs with their porous structure and special reticular framework can afford more channels and active sites for lithium ions migration and intercalation/ deintercalation. [95] Yin et al synthesized Ni-Mn-MOFs with a 3D spherical structure through a solvothermal method by using Ni(CH 3 COO) 2 •4H 2 O, Mn(CH 3 COO) 2 •4H 2 O, and biphenyl-3,3′,5,5′-tetracarboxylic acid (H 4 BPTC) as starting materials (Figure 1a), which was a pioneered work on anode material using pristine MOFs in LIBs.…”

Section: In Libsmentioning

confidence: 99%

Recent progress on construction and applications of metal‐organic frameworks‐based materials for lithium‐ion batteries and supercapacitors

Wei,

Zhang,

Wang

et al. 2024

Carbon Neutralization

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Metal‐organic frameworks (MOFs), a special sort of three‐dimensional crystalline porous lattices composed of organic multi‐site connectors and metal nodes, are characterized by unique porosity and high specific surface area, which have attracted a wide range of interest as electrode materials for the electrochemical energy storage devices in recent years. In this contribution, we outline the current research progress on the construction of pristine MOFs, MOF composites, and MOF derivatives and their applications as electrode materials in supercapacitors (SCs) and lithium‐ion batteries (LIBs). Specifically, we discuss the shortcomings of MOFs‐based electrode materials for SCs and LIBs. The innovative work on performance improvements by combining MOFs with other conductive materials and derivating MOFs into metal sulfides, metal oxides, metal phosphides, and porous carbon is also presented in detail. Finally, our perspectives on the challenges in the future for a grasp of the potential mechanisms are tentatively provided. This review will inspire more developments and applications of MOFs‐based electrode materials for electrochemical energy storage.

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Section: In Libsmentioning

confidence: 99%

Recent progress on construction and applications of metal‐organic frameworks‐based materials for lithium‐ion batteries and supercapacitors

Wei,

Zhang,

Wang

et al. 2024

Carbon Neutralization

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“…Transition metal phosphates (TMPs), like the MOF-derived metal oxides and metal sulfides discussed above, have become a significant study area for lithium-ion battery anodes due to their high specific capacity and safety. [200,201] The charging and discharging polarizations of transition metal phosphors(≈0.4 eV) have lower than other conversion anode materials, such as metal fluorides (≈1.1 eV), metal oxides (≈0.9 eV), and metal sulfides (≈0.7 eV). And the mass and the volume-specific capacity are higher than other materials.…”

Section: Mof-derived Metal Phosphidesmentioning

confidence: 99%

Recent Progress in MOF‐Derived Porous Materials as Electrodes for High‐Performance Lithium‐Ion Batteries

Song

Shi

Jiang

et al. 2023

Adv Funct Materials

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In recent years, metal‐organic frameworks, especially MOF‐based derivatives, have been regarded as one of the best candidate electrode materials for the next generation of advanced materials, due to high porosity, large surface area, modifiable functional groups as well as controllable chemical composition. This review presents the corresponding synthesis methods, structural design, and electrochemical performance of MOF‐derived materials, including metal oxides, metal sulfides, metal phosphides, and carbon materials, in high‐performance lithium‐ion batteries. Subsequently, the problems that exist in the current application of MOF‐based derivatives as electrodes in lithium‐ion batteries are discussed along with possible and feasible solutions. At last, some reasonable pathways and strategies for the design of MOF derivatives are also suggested.

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“…(1) Lithiation/delithiation process promotes charging and discharging, due to their effective active sites, and the chemical interaction in MOFs helps the stability and durability. (2) Interaction between metal nodes and organic ligand in 2D MOFs helps to improve tolerate volume expansion and shrinking which helps LIBs to their charging and discharging process, and (3) delocalization of charge and π-d conjugation provides nature electronic insulation which enchances the conductivity of 2D MOFs [257,[261][262][263].…”

Section: Challenges For 2d Mof As An Acidic Orr Catalystmentioning

confidence: 99%

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Nivetha

Sharma

Jana

et al. 2023

International Journal of Energy Research

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Metal–organic frameworks (MOFs), as a new generation of intrinsically porous extended crystalline materials formed by coordination bonding between the organic ligands and metal ions or clusters, have attracted considerable interest in many applications owing to their high porosity, diverse structures, and controllable chemical structure. Recently, 2D transition-metal- (TM-) based MOFs have become a hot topic in this field because of their high aspect ratio derived from their large lateral size and small thickness, as well as the advantages of MOFs. Moreover, 2D TM-based MOFs can act as good precursors to construct heterostructures with high electrical conductivity and abundant active sites for a range of applications. This review comprehensively introduces the widely adopted synthesis strategies of 2D TM-based MOFs and their composites/derivatives. In addition, this paper summarizes and highlights the recent advances in energy conversion and storage, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, CO2 reduction reaction, urea oxidation reaction, batteries, and supercapacitors. Finally, the challenges in developing these intriguing 2D layered materials and their composites/derivatives are examined, and the possible proposals for future directions to enhance the energy conversion and storage performance are reviewed.

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Metal–organic frameworks and their derivatives as electrode materials for Li-ion batteries: a mini review

Abstract: In recent decades, in order to obtain more excellent performance and wider application of rechargeable lithium-ion batteries (LIBs), researchers have been exploring potential electrode materials. MOFs possess attractive features, such...

Cited by 21 publications

References 95 publications

Recent progress on construction and applications of metal‐organic frameworks‐based materials for lithium‐ion batteries and supercapacitors

Recent progress on construction and applications of metal‐organic frameworks‐based materials for lithium‐ion batteries and supercapacitors

Recent Progress in MOF‐Derived Porous Materials as Electrodes for High‐Performance Lithium‐Ion Batteries

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

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