Metal organic frameworks derived porous lithium iron phosphate with continuous nitrogen-doped carbon networks for lithium ion batteries

Liu, Yuanyuan; Gu, Junjie; Zhang, Jinli; Ye, Feng; Dong, Lutao; Nie, Ning; Li, Wei

doi:10.1016/j.jpowsour.2015.11.022

Cited by 57 publications

(33 citation statements)

References 33 publications

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“…LiFePO 4 nanoparticles inlayed in NC networks (LFP/N-CNWs) were reported by Liu et al [92] By elaborately choosing MIL-100 (Fe) as both a template and starting material of Fe and C, they successfully prepared LFP/N-CNWs with an excellent surface area of 129 m 2 g −1 and high discharge capacities via carbonization at 600 °C under N 2 atmosphere (Figure 2a). The MIL-100 (Fe) was prepared using benzene trimesic acid (BTC) as a ligand.…”

Section: Wwwadvancedsciencenewscommentioning

confidence: 91%

“…Tan et al used MIL-100 (Fe) and dicyandiamide (DCDA) as both a template precursor and a N source to synthesize a N-doped graphene/Fe-Fe 3 C (NG/Fe-Fe 3 C) nanocomposite via a flexible one-pot method. [92] Copyright 2014, Elsevier. Shen et al successfully developed N-modified nanostructured carbons by annealing Cu-based metal-organic nanofibers (Cu-MONFs) under Ar atmosphere.…”

Section: Nitrogen-doped Carbonmentioning

confidence: 99%

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Metal‐Organic Framework‐Derived Carbons for Battery Applications

Zheng

Jin

et al. 2018

Advanced Energy Materials

197

112

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batteries, sodium-selenium (Na-Se) batteries, Li-tellurium (Li-Te) batteries, and Na-S batteries) have their own distinctive applications due to their various characteristics. To explore new materials with high performance, large studies have been devoted to the development of nextgeneration batteries.Porous carbon (PC) materials possess many unique properties due to their large surface areas, high conductivity, large pore volumes, high thermal stability, and surface functionalities, [22][23][24] leading to their wide use in energy storage and conversion. Traditionally, PC can be obtained via various methods, such as the direct heat treatment of organic precursors, hard template or nanocast methods, and soft template methods. However, the production of PC from these methods cannot be scaled-up because of certain barriers (disordered structure with wide size distributions, complicated processes, etc.). [23,25,26] Metal-organic frameworks (MOFs) have drawn wide research interest as a novel class of porous materials that are crystalline materials consisting of metal ions and organic ligands. [4,21,[27][28][29][30][31] Since the report on the MOF-templated synthesis of PC in 2008, [32] a large number of studies have been reported on the use of MOFs as suitable precursors/templates for carbon synthesis. [22,26,[33][34][35] At present, a large number of studies indicate that zeolitic imidazolate framework-8 (ZIF-8), MOF-5, MIL-125 (Ti) (MIL = Materials of Institute Lavoisier), and ZIF-67 with excellent thermal stability and unique porous structures are the more commonly used MOF precursors (Scheme 1). [3,36,37] All of them, ZIF-8, possessing nitrogen-containing ligands, has high porosity and thermal stability. [38][39][40] MOF-5 possesses excellent thermal stability, high porosity, and so on. [41] MIL-125, an active photocatalyst, includes cyclic octamers of TiO 2 octahedra. [42,43] ZIF-67 has a tunable pore aperture, highly stable structure, and catalytic activity. [37,44,45] The above-mentioned MOFs have been widely used for gas adsorption, molecular separation, catalysis, batteries, supercapacitors, and so on. [13,14,33] Moreover, carbon hybrids containing nanostructured metal species (e.g., metal oxides (MOs)) are likely to form under in situ carbonization conditions. [46] Compared with the carbonaceous materials from conventional precursors, MOF-derived carbon materials have significant advantages with high specific surface areas, tailorable porosities, unique morphologies, and easy functionalization with other heteroatoms. [14,23,31] For example, Xu and co-workers [47] obtained 1D carbon nanorods via the pyrolysis The applications of carbon and carbon-based materials with high porosity, high surface area, and functionalities based on metal-organic framework precursors and/or templates have attracted significant research interest in recent years, particularly in the field of batteries. The chemical and physical properties of carbon and carbon-based materials obtained by the heat treatment of various metal-organic ...

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Section: Wwwadvancedsciencenewscommentioning

confidence: 91%

Section: Nitrogen-doped Carbonmentioning

confidence: 99%

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Zheng

Jin

et al. 2018

Advanced Energy Materials

197

112

View full text Add to dashboard Cite

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“…A few works also reported MOF-derived materials as cathode materials of LIBs. 144,145 Although MOF-derived electrode materials show promise in terms of their much higher reversible capacities than that of commercial graphite, their practical application is hampered by the following issues: (1) MOF-derived materials to some extent inherit the high surface area and porosity of the MOF precursors. 14 The resultant large electrode/electrolyte interfacial area and low tap density lead to a low initial CE and volumetric energy density, which are harmful for the practical application, as discussed in the earlier section on LIBs under MOFs/MOF composites.…”

Section: Lithium-ion Batteriesmentioning

confidence: 99%

Metal-Organic Frameworks for Batteries

Zhao

Liang

Zou

et al. 2018

Joule

536

294

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Metal-organic frameworks (MOFs) and their derivatives are two developing families of functional materials for energy storage and conversion. Their high porosity, versatile functionalities, diverse structures, and controllable chemical compositions offer immense possibilities in the search for adequate electrode materials for rechargeable batteries. Despite these advantageous features, MOFs and their derivatives as electrode materials face various challenging issues, which impede their practical applications. From this perspective, we present both the opportunities and challenges that MOFs/MOF composites and MOF-derived materials bring to rechargeable batteries, including lithium-ion batteries, lithium-sulfur batteries, lithium-oxygen batteries, and sodium-ion batteries. By discussing the development of MOFs/MOF composites and MOF-derived materials in each battery system, some design principles that dominate the specific electrochemical behaviors are outlined, with the key requirements that a practical electrode should fulfill. At the end, a basic guidance and future directions for further development are provided.

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“…However, considering the cost of electrode materials, researchers demand a low‐cost material for a wide spread application. A material contains lithium iron phosphate (LiFePO 4 ) nanoparticles and nitrogen‐doped carbon networks (LFP/N‐CNWs) would be appropriate for LIBs owing to its reasonable price, desirable theoretical discharge capacity (≈170 mA h g −1 ), and environmental benignity according to Liu et al's exploration . The porous LFP/N‐CNW composites used a unique Fe‐based MOF (MIL‐100) to serve as sources of Fe and C and the template of the final composite.…”

Section: Batteriesmentioning

confidence: 99%

Applications of Metal–Organic‐Framework‐Derived Carbon Materials

et al. 2018

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production, especially for hydroelectricity, sunlight, and wind energy, which cannot be gathered or released when they are needed. [5][6][7][8] Electrochemical energy storage devices provide a promising approach for the storage of electric energy from these sources. [9][10][11] Currently, carbonaceous materials have attracted much interest for their extensive applications including adsorption, [12] catalysis, [13] batteries, [14] fuel cells, [15,16] supercapacitors, [17,18] and drug delivery and imaging. [19] In addition, some sensors are also one of the important applications of carbonaceous materials, because they are closely related to human health. [20,21] For instance, Emran and co-workers [22] constructed ultrasensitive biosensors with N-doped mesoporous carbon (NMC)-based electrodes for in vitro monitoring of DA released from living cells. With the further study of the experiment, they also designed a series of S-doped carbon materials for a wider detection of DA, UA (uric acid), and AA (ascorbic acid). [23,24] The advantages of easy preparing, nontoxic and excellent electrical conductivity of carbonaceous materials, which are rare among energy storage materials, make carbonaceous materials superior to most of the energy storage materials. [25][26][27] There are varieties of approaches for the preparation of carbon materials, such as directly carbonizing from organic precursors, physically or chemically carbonizing from carbon, template methods using zeolites and mesoporous silica, solvothermal and hydrothermal methods with elevated temperature, the electrical arc methods, and chemical vapor decomposition (CVD) methods. [28][29][30][31][32][33][34] Among all these approaches, directly carbonizing from organic precursors is the most frequently used method to prepare nanoporous carbons (NPCs) due to its flexibility and simplicity. [35][36][37] However, these NPC materials present certain drawbacks, such as low surface areas, disordered structures, and ununiformed sizes, which will greatly limit their applications. [25] As studies have progressed, researchers found that carbon materials derived from metalorganic frameworks (MOFs) could overcome these limitations.Metal-organic frameworks, which are also named porous coordination polymers (PCPs), are crystalline porous materials with periodic network structures formed by metal ions (or metal clusters) and organic ligands. [38][39][40][41][42] They are usually prepared by solvothermal methods and used as precursors or templates to form nanostructured materials. [43][44][45] So far, many researchers have highlighted the advantages of MOFs. For Carbon materials derived from metal-organic frameworks (MOFs) have attracted much attention in the field of scientific research in recent years because of their advantages of excellent electron conductivity, high porosity, and diverse applications. Tremendous efforts are devoted to improving their chemical and physical properties, including optimizing the morphology and structure of the carbon materials, compositing them wi...

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Metal organic frameworks derived porous lithium iron phosphate with continuous nitrogen-doped carbon networks for lithium ion batteries

Cited by 57 publications

References 33 publications

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Metal‐Organic Framework‐Derived Carbons for Battery Applications

Metal-Organic Frameworks for Batteries

Applications of Metal–Organic‐Framework‐Derived Carbon Materials

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