Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis

Jin, Hong-Guang; Zhao, Peng-Cheng; Qian, Yunyang; Xiao, Juan-Ding; Chao, Zi-Sheng; Jiang, Hai-Long

doi:10.1039/d4cs00095a

Chem. Soc. Rev.

2024

DOI: 10.1039/d4cs00095a

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Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis

Hong-Guang Jin,

Peng-Cheng Zhao,

Yunyang Qian

et al.

Abstract: This review summarizes recent advances on metal–organic framework-based materials for organic transformations by photocatalysis and photothermal catalysis.

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Cited by 8 publications

References 439 publications

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Reticular Materials for Photocatalysis

Sun,

Qian,

et al. 2024

Advanced Materials

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Photocatalysis leverages solar energy to overcome the thermodynamic barrier, enabling efficient chemical reactions under mild conditions. It can greatly reduce reliance on traditional energy sources and has attracted significant research interest. Reticular materials, including metal‐organic frameworks (MOFs) and covalent organic frameworks (COFs), represent a class of crystalline materials constructed from molecular building blocks linked by coordination and covalent bonds, respectively. Reticular materials function as heterogeneous catalysts, combining well‐defined structures and high tailorability akin to homogeneous catalysts. In this review, the regulation of light absorption, charge separation, and surface reactions in the photocatalytic process through precise molecular‐level design based on the features of reticular materials is elaborated. Notably, for MOFsmicroenvironment modulation around catalytic sites affects photocatalytic performance is delved, with emphasis on their unique dynamic and flexible microenvironments. For COFs, the inherent excitonic effects due to their fully organic nature is discussed and highlight the strategies to regulate excitonic effects for charge‐ and/or energy‐transfer‐mediated photocatalysis. Finally, the current challenges and future directions in this field, aiming to provide a comprehensive understanding of how reticular materials can be optimized for enhanced photocatalysis is discussed.

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Reticular Materials for Photocatalysis

Sun,

Qian,

et al. 2024

Advanced Materials

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Flexible Triboelectric Nanogenerators Based on Cadmium Metal–Organic Framework/Eethyl Cellulose Composites as Energy Harvesters for Selective Photoinduced Bromination Reaction

Zhang,

Huang,

Tao

et al. 2024

Small

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The fabrication of self‐driven systems with flexibility and tunable output for organic photoinduction is highly desirable but challenging. In this study, a 3D cadmium metal–organic framework (Cd‐MOF) is synthesized and used as a filler for ethyl cellulose (EC) to create mechanically durable and flexible Cd‐MOF@EC composite films. Due to its well‐established platform with periodically precise structure nature, the outputs of Cd‐MOF‐based TENG are much higher than those of ligand‐based TENGs. Furthermore, composite films with different doping ratios of Cd‐MOF are employed to assemble Cd‐MOF@EC‐based triboelectric nanogenerators (TENGs). The results reveal that a doping ratio of 10 wt.% Cd‐MOF in Cd‐MOF@EC provides the highest TENG output. Subsequently, a flexible 10 wt.% Cd‐MOF@EC‐based TENG (FCEC‐TENG), working in the contact‐separation model, is constructed to harvest mechanical energy from the human body, demonstrating excellent output performance and stability. The energy harvested from FCEC‐TENG can directly illuminate 14 commercial white light‐emitting diodes (LEDs), providing visible light for the photoinduction of the bromination reaction, and generating bromide with good yield and tolerance. This study presents an effective method for constructing flexible MOF‐based TENG for self‐powered photoinduced organic transformation systems.

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Hybrid Metal-Organic Frameworks (MOFs) for Various Catalysis Applications

Virender,

Pandey,

Singh

et al. 2024

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Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis

Abstract: This review summarizes recent advances on metal–organic framework-based materials for organic transformations by photocatalysis and photothermal catalysis.

Cited by 8 publications

References 439 publications

Reticular Materials for Photocatalysis

Reticular Materials for Photocatalysis

Flexible Triboelectric Nanogenerators Based on Cadmium Metal–Organic Framework/Eethyl Cellulose Composites as Energy Harvesters for Selective Photoinduced Bromination Reaction

Hybrid Metal-Organic Frameworks (MOFs) for Various Catalysis Applications

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