2016
DOI: 10.1016/j.cej.2015.10.098
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Metal–organic frameworks with high working capacities and cyclic hydrothermal stabilities for fresh water production

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Cited by 72 publications
(43 citation statements)
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“…With the exception of MIL-127(Fe), the water-sorption properties of these MOFs were previously reported, [3,12,17,[30][31][32][33][34][35] with interesting results in terms of water-sorptionc apacity and lowtemperature regeneration. Moreover, the hydrophilic character of someM OFs [MIL-125(Ti)-NH 2 ,U iO-66(Zr)-NH 2 ]c ould be enhanced throught he introduction of hydrophilic amino groups on the organic spacer.H erein, we aimed to comparet hese MOFs and zeolite 13X [29] (see Table 1) as potential physicala dsorbentm aterials fore nergy-storage applications (the full characterization of the MOFs is given in the Supporting Information, Figures S1-S23).W ef irst measuredt heir cycling loading lifts using the typical conditions of as easonal energy-storage device.…”
Section: Resultsmentioning
confidence: 97%
“…With the exception of MIL-127(Fe), the water-sorption properties of these MOFs were previously reported, [3,12,17,[30][31][32][33][34][35] with interesting results in terms of water-sorptionc apacity and lowtemperature regeneration. Moreover, the hydrophilic character of someM OFs [MIL-125(Ti)-NH 2 ,U iO-66(Zr)-NH 2 ]c ould be enhanced throught he introduction of hydrophilic amino groups on the organic spacer.H erein, we aimed to comparet hese MOFs and zeolite 13X [29] (see Table 1) as potential physicala dsorbentm aterials fore nergy-storage applications (the full characterization of the MOFs is given in the Supporting Information, Figures S1-S23).W ef irst measuredt heir cycling loading lifts using the typical conditions of as easonal energy-storage device.…”
Section: Resultsmentioning
confidence: 97%
“…A series of isostructural UiO-66(Zr) with different functional groups such as -NH2, -OH, and -(OH)2 were employed to functionalize the BDC linker to investigate the hydrophilic effect of the groups. [74] All the functionalized UiO-66(Zr) materials showed enhanced water adsorption in the low P/P0 relative pressure due to the augmented interactions with water molecules, leading to isotherms that approached the type I shape (Fig.11a). However, water adsorption of the functionalized UiO-66(Zr) materials in the high P/P0 decreased significantly compared with the original UiO-66(Zr) as a consequence of the decreased surface area due to the insertion of bulky groups in the pores.…”
Section: Functionalized Mofs Bearing Ligand Functional Groupmentioning
confidence: 99%
“…However, in order to further improve AHPs performance, the adsorption ability of MIL‐100(Fe) at low RH (10%‐30%) still needs to be increased. The modification of MOFs usually introduces the hydrophilic groups such as nitro (NO 2 ), amino (NH 2 ) and hydroxyl (OH) on the organic ligands 21,25 . However, the complicated modification process seems to limit its use.…”
Section: Introductionmentioning
confidence: 99%
“…However, the complicated modification process seems to limit its use. Only a few MOFs, such as MIL‐101(Cr), 21,26 MIL‐125 27 and UIO‐66, 25 were reported.…”
Section: Introductionmentioning
confidence: 99%