Nano Online 2016
DOI: 10.1515/nano.0034.00056
|View full text |Cite
|
Sign up to set email alerts
|

Metal oxide and bimetallic nanoparticles in ionic liquids: synthesis and application in multiphase catalysis

Abstract: Ionic liquids (ILs) are well established as solvents and stabilizing agents for the synthesis of metallic nanoparticles (NPs) in general. The physicochemical properties of ILs and the supramolecular organization in the liquid state are capable of directing the growth of transition metal NPs generated in situ and to subsequently protect and stabilize them. Until now, many different NPs have been successfully synthesized within these media; however, the synthesis of metal oxide and bimetallic alloy or core-shell… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

0
5
0

Year Published

2020
2020
2020
2020

Publication Types

Select...
3

Relationship

0
3

Authors

Journals

citations
Cited by 3 publications
(5 citation statements)
references
References 32 publications
0
5
0
Order By: Relevance
“…In contrast to random mixtures already addressed by MInChI, complex NMs are well-defined mixtures whose structures are based on the structure of the ‘solvent’ (the major metal core structure of the NM) and changes induced by doping with another element. Bimetallic NMs can be alloys (i.e., homogeneous crystalline mixture of both metals), fused clusters, core-shell, or simply mixtures of monometallic NMs, shown schematically in Figure 5 [ 130 ]. Alloys can be predicted from the miscibility of metals.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…In contrast to random mixtures already addressed by MInChI, complex NMs are well-defined mixtures whose structures are based on the structure of the ‘solvent’ (the major metal core structure of the NM) and changes induced by doping with another element. Bimetallic NMs can be alloys (i.e., homogeneous crystalline mixture of both metals), fused clusters, core-shell, or simply mixtures of monometallic NMs, shown schematically in Figure 5 [ 130 ]. Alloys can be predicted from the miscibility of metals.…”
Section: Resultsmentioning
confidence: 99%
“…MetalA x MetalB 1−x O y . Structural representation must capture morphological differences in tier 1 of Figure 1 [ 130 ].…”
Section: Figurementioning
confidence: 99%
“…The functional properties can be tuned by modifying the size, shape and composition of the synthon along by studying state of art of the synthetic method with pH control which helps to design a device for their technological applications with synergic effects to control the nucleation and its growth. Understanding the nucleation and growth process by self-assembling helps to integrate functional structures via optimizing hydrolysis and kinetic process based on electro-negativity of metal ion (Klein 1988;Brinker and Scherer 1990;Sakka 2004;Szafert et al 2008;Grado-Caffaro 2008;Bilecka and Niederberger 2010;Bang and Suslick 2010;Liu et al 2011;Hassan et al 2012;Precht and Campbel 2013;An and Soorrjai 2015).…”
Section: Resultsmentioning
confidence: 99%
“…Bimetallic oxide exhibits novel physico-chemical properties that can be tailored with composition, size and atomic ordering. Metal ion plays a crucial role in balancing the thermodynamic-kinetic parameters to control functional behavior due to its coordination with metal ions and also tuning of surface morphology leads to the formation of nanostructure material with high performance (Klein 1988;Brinker and Scherer 1990;Kessler 2003;Sakka 2004;Szafert et al 2008;Bilecka and Niederberger 2010;Hassan et al 2012;Precht and Campbel 2013;An and Soorrjai 2015). During synthesis, we focused the phase separation with non-aggregated particles by retaining stoichiometric ratio under control.…”
Section: Introductionmentioning
confidence: 99%
“…The presence of two nontoxic elements helps to maintain colloidal stability under physiochemical condition in human cell for its wide use in screening at the particular pH, which depends on favorable shape and size retaining the surface morphology intact. The use of ZnBaO 2 nanopowder has become a motivating area for research due to its volume-cost-effective relation with the macroscopic quantum tunnel effect (Trusova et al 2012;Hayashi and Hakata 2010;Cao and Wang 2004;Vollath 2008;Lalena and Cleary 2010;Fan et al 2015;Klabunde and Richards 2012;Muller et al 2007;Betke and Kickelbick 2014;Athar 2008;Kickelbick and Schubert 2002;Prechtl and Campbell 2013;Naumann 2009;Mackenzie and Bescher 2007;Edler 2004;Klein 1988;Talapin 2012;Lee et al 2013;Pang et al 2013;Wang et al 2005;Pilenic 2007).…”
Section: Introductionmentioning
confidence: 99%