Metal-vapour synthesis of phospha-organometallic compounds: reaction of nickel atoms with the phospha-alkyne tBuCP. Structural characterisation of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)], a derivative of the novel, aromatic phosphirenyl cation
“…Sc [3], Ti [4,5], V [6], Cr [17], Mn [18], Fe [7][8][9][10][11][12][13], Co [19], Ni [21][22][23][24][25], Ru [13][14][15][16], and Rh [16,20]) and main group elements (e.g. Ga [26], In [27][28][29], Tl [26], Sr [30], and Pb [31]).…”
“…Sc [3], Ti [4,5], V [6], Cr [17], Mn [18], Fe [7][8][9][10][11][12][13], Co [19], Ni [21][22][23][24][25], Ru [13][14][15][16], and Rh [16,20]) and main group elements (e.g. Ga [26], In [27][28][29], Tl [26], Sr [30], and Pb [31]).…”
Geladen! Die Kombination von MeBABAR‐Phos und Methyltriflat ergibt ein aminostabilisiertes Phosphiranyliumion (siehe Bild; C grau, N blau, P orange), das verschiedene nucleophile Additionsreaktionen eingeht. Dabei bilden sich P‐substituierte Phosphirane sowie ein Phosphiranyliumkation, das durch ein N‐heterocyclisches Carben stabilisiert wird.
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