“…21,22 As a consequence, these Janus systems are ideal candidate materials for spintronics and valleytronics. Therefore, modifying conventional centrosymmetric 2D materials to form Janus structures is an effective method to generate a piezoelectric response, 23,24 RSS, 20 and valley polarization. 21,22 In recent years, a new family of 2D materials, group-VIA elemental 2D materials, with high carrier mobility, high photoconductivity, thermoelectricity, and piezoelectricity 23,25 have appeared in people's field of vision.…”