Metallkomplexe mit biologisch wichtigen Liganden, LXVI [1]. Rhodium(III)-, Iridium(III)-, Palladium(II)-, Platin(II)- und Gold(I)-Komplexe von N-(2,3,4,6-Tetra-O-acety-β-ᴅ-glucopyranosyl)-thiocarbamatestern und β-ᴅ-Glucopyranosylthioharnstoff / Metal Complexes of Biologically Important Ligands, LXVI [1]. Rhodium(III), Iridium(III), Palladium(II), Platinum(II), Gold(I) Complexes of N-(2,3,4,6-Tetra-O-acetyl-β-ᴅ-glucopyranosyl)-thiocarbamate Esters and β-ᴅ-Glucopyranosylthiourea

Abstract

From N-(2,3,4,6-tetra-O-acetyl-β-ᴅ-glucopyranosyl)-thiocarbamate esters (L1) the complexes (η5-C5Me5)(Cl2)M(L1) (M = Rh, Ir), , trans-(n-Bu3P)(Cl)2M(L1) (M = Pd, Pt), trans-Cl2Pt(L1)2, [(Ph3P)2(Cl)Pt(L1)]+, Cl2Pt(μ-L1)PtCl2 and ClAuL1 have been obtained. β-ᴅ-glucopyranosylthiourea (L2) forms the complexes (η5-C5Me5)(Cl)2M(L2) (M = Rh, Ir), (Cl)Me2NCH2C6H4)Pd(L2), (Et3P)Cl2Pd(L2) and Cl2M(L2)2(M = Pd, Pt).