The band structures of several analogous superconducting A‐15 type solid compounds, Nb3X (X=Si, Ge, Sn, Pb), have been calculated by use of the tight‐binding method within the Extended Hückel approximation (EHT). By analysis of their energy bands, densities of states and crystal orbital overlap populations, the dependence of the superconducting transition temperatures (Tc) on the electronic structures and bondings is qualitatively elucidated.