2019
DOI: 10.1002/ange.201905913
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Metallmodifizierte Nukleinsäuren: Metallvermittelte Basenpaare, ‐tripel und ‐tetraden

Abstract: Das Einbringen von Metallionen in Nukleinsäuren mittels metallvermittelter Basenpaare stellt eine vielversprechende und weit verbreitete Methode zur ortsspezifischen Modifizierung dieser selbstassemblierenden Supramoleküle mit metallbasierter Funktionalität dar. In den vergangenen 20 Jahren wurden zahlreiche solcher Nukleosid‐Surrogate entwickelt, die die Bandbreite an Metallen durch perfekt zugeschnittene Metallbindungsstellen erweitert haben. In jüngster Vergangenheit rückten künstliche, von natürlichen Puri… Show more

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Cited by 15 publications
(1 citation statement)
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References 126 publications
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“…Metal‐mediated base pairing has been studied for more than two decades [1–8] for potential applications ranging from molecular switches [9–11] and wires [12–16] to sequence recognition [17–21] to expansion of the genetic code [22–26] . Of the numerous metal ions used in these studies, Ag(I), Cu(II) and Hg(II) have met with the greatest success.…”
Section: Introductionmentioning
confidence: 99%
“…Metal‐mediated base pairing has been studied for more than two decades [1–8] for potential applications ranging from molecular switches [9–11] and wires [12–16] to sequence recognition [17–21] to expansion of the genetic code [22–26] . Of the numerous metal ions used in these studies, Ag(I), Cu(II) and Hg(II) have met with the greatest success.…”
Section: Introductionmentioning
confidence: 99%