Metalloporphyrin cis effects and the coordination properties of benzporphyrin complexes. Ligand binding to octamethyltetrabenzprophyrinzinc(II)

Reimer, Kenneth J.; Reimer, Monica

doi:10.1016/s0020-1693(00)88513-8

Inorganica Chimica Acta

1981

DOI: 10.1016/s0020-1693(00)88513-8

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Metalloporphyrin cis effects and the coordination properties of benzporphyrin complexes. Ligand binding to octamethyltetrabenzprophyrinzinc(II)

Kenneth J. Reimer¹,

Monica Reimer²

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1981

1993

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Cited by 5 publications

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Organometallic complexes with biological molecules. I. Diorganotin(IV)chloro protoporphyrin IX complexes: Solid‐state and solution‐phase characterization

Pellerito

Maggio

et al. 1993

Applied Organom Chemis

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Protoporphyrin IX (H,PPIX) complexes of diorganotin(1V)chloro moieties with formula (R2SnC1),H,PPIX (R = Me, Bu and Ph) have been obtained and their solid-state and solution-phase configurations have been studied through spectroscopic investigations.Coordination of the side-chain carboxylates of H4PPIX to R,Sn(IV)CI moieties, with bridging carboxylate (COO-) has been inferred by comparison of the free and coordinated H,PPIX IR spectra, while the occurrence of a five-coordinated tin(1V) atom in a cis-R, trigonal bipyramidal structure has been deduced, for all of the synthesized complexes, by rationalization of the nuclear quadrupole splitting parameters, according to the point-charge model formalism. Finally, the solution-phase spectral features of (R,SnCI),-H,PPIX are in agreement with the monomeric character of the protoporphyrin IX, under the experimental conditions used.

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Organometallic complexes with biological molecules. I. Diorganotin(IV)chloro protoporphyrin IX complexes: Solid‐state and solution‐phase characterization

Pellerito

Maggio

et al. 1993

Applied Organom Chemis

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: METALLOPORPHYRIN CIS EFFECTS AND THE COORDINATION PROPERTIES OF BENZPORPHYRIN COMPLEXES. LIGAND BINDING TO OCTAMETHYLTETRABENZPORPHYRINZINC(II)

Reimer¹,

Reimer²

1981

Chemischer Informationsdienst

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Zinc and cadmium

Constable¹

1982

Coordination Chemistry Reviews

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Metalloporphyrin cis effects and the coordination properties of benzporphyrin complexes. Ligand binding to octamethyltetrabenzprophyrinzinc(II)

Cited by 5 publications

References 19 publications

Organometallic complexes with biological molecules. I. Diorganotin(IV)chloro protoporphyrin IX complexes: Solid‐state and solution‐phase characterization

Organometallic complexes with biological molecules. I. Diorganotin(IV)chloro protoporphyrin IX complexes: Solid‐state and solution‐phase characterization

ChemInform Abstract: METALLOPORPHYRIN CIS EFFECTS AND THE COORDINATION PROPERTIES OF BENZPORPHYRIN COMPLEXES. LIGAND BINDING TO OCTAMETHYLTETRABENZPORPHYRINZINC(II)

Zinc and cadmium

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