2022
DOI: 10.1039/d1nj05146f
|View full text |Cite
|
Sign up to set email alerts
|

Metallosupramolecular polymers formed with silver(i) ions in aqueous solution

Abstract: We report supramolecular polymers of a terpyridine-based ligand with an alanine moiety (L) at three different concentrations of AgNO3 (0, 0.5, and 1.0 equiv.) in a mixture of H2O and...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
4
0

Year Published

2023
2023
2024
2024

Publication Types

Select...
4

Relationship

1
3

Authors

Journals

citations
Cited by 4 publications
(4 citation statements)
references
References 56 publications
0
4
0
Order By: Relevance
“…An interesting family of chiral aggregates are the metallo‐supramolecular polymers, in which transition metals or lanthanides are combined to organic ligands to generate linear metallopolymers that fold into helical structures [48–55] . In other cases, the metal ion is contained in the monomer used as a building block [56] that is later self‐assembled into a chiral aggregate through the activation of supramolecular interactions [57] . In this work, we will explore the possibility of triggering the axial chiral supramolecular self‐assembly of a molecularly dissolved chiral building block by using a metal ion as external stimulus.…”
Section: Methodsmentioning
confidence: 99%
See 2 more Smart Citations
“…An interesting family of chiral aggregates are the metallo‐supramolecular polymers, in which transition metals or lanthanides are combined to organic ligands to generate linear metallopolymers that fold into helical structures [48–55] . In other cases, the metal ion is contained in the monomer used as a building block [56] that is later self‐assembled into a chiral aggregate through the activation of supramolecular interactions [57] . In this work, we will explore the possibility of triggering the axial chiral supramolecular self‐assembly of a molecularly dissolved chiral building block by using a metal ion as external stimulus.…”
Section: Methodsmentioning
confidence: 99%
“…[48][49][50][51][52][53][54][55] In other cases, the metal ion is contained in the monomer used as a building block [56] that is later self-assembled into a chiral aggregate through the activation of supramolecular interactions. [57] In this work, we will explore the possibility of triggering the axial chiral supramolecular self-assembly of a molecularly dissolved chiral building block by using a metal ion as external stimulus. To do that, we envisioned a chiral phenylacetylene (PA) monomer complexed to a metal ion such as Ag(I).…”
mentioning
confidence: 99%
See 1 more Smart Citation
“…Furthermore, we have reported Ag + -assisted chiral supramolecular polymers accompanying helical inversion and/or morphology transformation. 48 Although a variety of Ag(I)coordinated polymeric structures have been reported, [47][48][49][50][51][52][53] the influence of the morphology of Ag + -coordinated supramolecular architectures based on building blocks bearing trans and cisdouble bonds in the alkyl chain has not been reported to date. In this communication, we report the influence of morphology changes of Ag + -coordinated supramolecular polymers of a terpyridine-based ligand bearing an alanine moiety and trans-(trans-L) and cis-(cis-L) double bonds in the alkyl chain, prepared using Ag + (0.5 and 1.0 equiv.)…”
mentioning
confidence: 99%