Metallosurfactant based Pd–Ni alloy nanoparticles as a proficient catalyst in the Mizoroki Heck coupling reaction

Abstract

A highly efficient, operationally simple, green catalytic approach using Pd–Ni alloy nanoparticles for Mizoroki Heck coupling.

Nickel Nanocatalysis: An Efficient Tool for Heck Reaction

“…Pd−Ni alloy nanoparticles (NPs) from palladium and nickel metallo‐surfactants were generated and employed in industrially significant Heck coupling reaction under the condition of microwave irradiation (Scheme 9). [30] The different techniques like EDX, XDS, ICP analysis were availed in determining the morphological properties. The catalytic activity of Pd−Ni alloy NPs in Heck coupling reaction between alkenes exemplified to be styrenes, ethyl acrylates 2 and substituted aryl halides 1 were developed under the conditions such as 1.5 mmol.…”

A flower-like ZnO–Ag2O nanocomposite for label and mediator free direct sensing of dinitrotoluene

“…Such properties possessed by these materials can be attributed to a large surface area to volume ratio, resulting in the surface having a greater number of active atoms. [16][17][18] Nanostructured metal oxides have also shown great potential in biosensing applications. 19,20 Hence, metal oxidebased nanocomposites can be used as suitable materials for electrode modication.…”

Unravelling donor–acceptor film morphology formation for environmentally-friendly OPV ink formulations

“…[6][7][8] Green solvents are environmentally friendly solvents which pose low environmental impact in both production and use, and can include bio-solvents. 9 The transition to green solvent processing and green synthetic techniques has been reported in various fields, including catalyst development, 10,11 synthesis of inorganic semiconductors for solar cell applications, 12 medicinal chemistry, 13,14 and analytical chemistry. 15 Shifting from halogenated solvents (such as chloroform, chlorobenzene and o-dichlorobenzene) to green solvents requires substantial film microstructure optimisation, 16,17 due to the vast effect that the casting solvent has on self-assembly of the complex donor-acceptor film morphology for these systems.…”