Consider a non-autonomous continuous-time linear system in which the timedependent matrix determining the dynamics is piecewise constant and takes finitely many values A 1 , . . . , A N . This paper studies the equality cases between the maximal Lyapunov exponent associated with the set of matrices {A 1 , . . . , A N }, on the one hand, and the corresponding ones for piecewise deterministic Markov processes with modes A 1 , . . . , A N , on the other hand. A fundamental step in this study consists in establishing a result of independent interest, namely, that any sequence of Markov processes associated with the matrices A 1 , . . . , A N converges, up to extracting a subsequence, to a Markov process associated with a suitable convex combination of those matrices.