“…Some researches showed that chamber technique overestimates the fluxes relative to the thin boundary layer technique, primarily because the latter only considers diffusion across the airewater interface (Richey et al, 1988;Devol et al, 1990). Similarly, Bubier et al (1993) also suggested the difference between chamber method and thin boundary layer technique results from the absence of ebullition, an important flux mechanism, especially to CH 4 , in the latter method. According to the estimation of a eutrophic lake in Priest Pot, UK, CH 4 92e98% is released by ebullition and CO 2 98.8e99.7% is released by diffusion (Casper et al, 2000).…”