Methane oxidative carbonylation catalyzed by rhodium chalcogen halides over carbon supports

Kosmambetova, G. R.; Strizhak, P. E.; Gritsenko, V. I.; Волков, С. В.; Khar’kova, L. B.; Yanko, O. G.; Korduban, A. M.

doi:10.1016/s1003-9953(08)60018-3

Cited by 13 publications

(2 citation statements)

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“…Rh‐doped FePO 4 catalyst was found to be active towards directly converting methane to methyl acetate in a single step via the reaction with N 2 O and CO, and the dual site containing Rh(III) species and FePO 4 in close proximity was proposed to account for methyl acetate formation ,. In the gas phase methane oxidative carbonylation, Rh‐based catalysts such as rhodium chalcogen halides and rhodium chalcogenides over silica supports exhibited high activity for the formation of oxygenates (methanol, methyl acetate and acetic acid) ,…”

Section: Catalytic Heterogeneous Reactionsmentioning

confidence: 99%

Rh‐Based Nanocatalysts for Heterogeneous Reactions

Luo

Peng

et al. 2018

ChemNanoMat

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Rhodium (Rh) is well‐known for its catalytic application in diverse industrial reactions such as methane conversion, hydrogen generation, and olefin hydroformylation. Compared to homogeneous catalysts, heterogeneous Rh‐based nanocatalysts are facilely separated and collected after reactions, thus being more compatible for industrialization. To this end, the development of active and stable heterogeneous Rh‐based catalysts has received everlasting interest. In this review, we focus on the synthesis and catalytic application of Rh‐based nanocatalysts for heterogeneous catalysis. Recent efforts in the design and fabrication of Rh‐based nanocatalysts are highlighted. Various synthetic strategies and protocols for shape‐controlled synthesis of Rh‐based nanocrystals and supported Rh‐based nanocatalysts are overviewed. In addition, we introduce methane conversion, hydrogen generation, and olefin hydroformylation as three typical catalytic applications of the Rh‐based nanocatalysts, and provide insights into the catalytic mechanisms involved. The remaining challenges and future prospects for the Rh‐based heterogeneous nanocatalysts are also discussed. This review offers a guideline for future research on Rh‐based nanocatalysts for heterogeneous catalysis.

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Section: Catalytic Heterogeneous Reactionsmentioning

confidence: 99%

Rh‐Based Nanocatalysts for Heterogeneous Reactions

Luo

Peng

et al. 2018

ChemNanoMat

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“…Our group has used poly(hydroxyethyl methacrylate) (pHEMA) as the solid carrier because it contains abundant hydroxyls, which are highly polar and active. The salen monomer was incorporated onto pHEMA by a coordinate bond similar to that reported in the literature from other methods including non-covalent immobilization, inorganic graft, and copolymerization [15].…”

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confidence: 99%