A simple terahertz (THz) cavity and a TEA CO 2 laser for the optically pumped THz emission is studied experimentally. To obtain high peak power of pump laser, pressure ratios of gas mixture in the cavity of the TEA CO 2 laser are discussed. When CH 3 OH are pumped by the 9P(16) and 9P(36) CO 2 laser lines, the generation of terahertz radiation with energy as high as 353 µJ and 307 µJ are obtained, respectively. The corresponding photon conversion efficiencies are 0.705% and 0.29%. Meanwhile, higher peak power of pump laser effectively improves the photon conversion efficiency. And the optimum THz laser pressure increases with narrower pulse width of pump laser.