Methanol production from CO2 using solar-thermal energy: process development and techno-economic analysis

Abstract

We describe a novel solar-based process for the production of methanol from carbon dioxide and water. The system utilizes concentrated solar energy in a thermochemical reactor to reenergize CO 2 into CO and then water gas shift (WGS) to produce syngas (a mixture of CO and H 2 ) to feed a methanol synthesis reactor. Aside from the thermochemical reactor, which is currently under development, the full system is based on well-established industrial processes and component designs. This work presents an initial assessment of energy efficiency and economic feasibility of this baseline configuration for an industrial-scale methanol plant. Using detailed sensitivity calculations, we determined that a breakeven price of the methanol produced using this approach would be 1.22 USD/kg; which while higher than current market prices is comparable to other renewable-resource-based alternatives. We also determined that if solar power is the sole primary energy source, then an overall process energy efficiency (solar-to-fuel) of 7.1% could be achieved, assuming the solar collector, solar thermochemical reactor sub-system operates at 20% sunlight to chemical energy efficiency. This 7.1% system efficiency is significantly higher than can currently be achieved with photosynthesis-based processes, and illustrates the potential for solar thermochemical based strategies to overcome the resource limitations that arise for low-efficiency approaches. Importantly, the analysis here identifies the primary economic drivers as the high capital investment associated with the solar concentrator/reactor sub-system, and the high utility consumption for CO/CO 2 separation. The solar concentrator/reactor sub-system accounts for more than 90% of the capital expenditure. A life cycle assessment verifies the opportunity for significant improvements over the conventional process for manufacturing methanol from natural gas in global warming potential, acidification potential and non-renewable primary energy requirement provided balance of plant utilities for the solar thermal process are also from renewable (solar) resources. The analysis indicates that a solar-thermochemical pathway to fuels has significant potential, and points towards future research opportunities to increase efficiency, reduce balance of plant utilities, and reduce cost from this baseline. Particularly, it is evident that there is much room for improvement in the development of a less expensive solar concentrator/reactor sub-system; an opportunity that will benefit from the increasing deployment of concentrated solar power (electricity). In addition, significant advances are achievable through improved separations, combined CO 2 and H 2 O splitting, different end products, and greater process integration and distribution. The baseline investigation here establishes a methodology for identifying opportunities, comparison, and assessment of impact on the efficiency, lifecycle impact, and economics for advanced system designs.

Solar thermochemical splitting of water to generate hydrogen

“…H 2 production through the low-temperature WGS reaction is thermodynamically favorable due to this cross-over in stability. Maravelias and coworkers (16,17) assessed the three main thermochemical fuel production systems shown in Fig. S2.…”

“…The loss of efficiency of systems i and ii is due to the energyintensive CO 2 /CO separation and to the unfavorable thermodynamics of the RWGS reaction, respectively. The efficiency of system iii is greater than that of the other two because the requirement of CO 2 /CO separation is reduced significantly and the H 2 :CO ratio is set by the distribution of the solar heating units (16,17). Two-step cycles can make use of stoichiometric or nonstoichiometric oxides.…”

Simulation and process integration for tert-amyl-methyl ether (TAME) synthesis

“…Techno-economic analysis is performed with Aspen Process Economic Analyzer ® v8.4 (Aspen, 2013), only for the best case study (CS3), selected according to results obtained by previous analyses types (Kim et al, 2011). The input data for equipment, operating, and capital cost estimation are the results from Aspen HYSYS ® simulations.…”

Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming

“…Reusing and recycling CO 2 in the process of synthetic fuel production would add value to these chemicals and reduce the uptake from the fossil-based natural resources [6] which is the principal of another conceptual framework known as ''methanol economy" [7]. This concept can be further empowered by capturing large CO 2 emissions from power plants and other process industries to be converted and utilized as a feedstock for a wide variety of fuels and petrochemicals [8,9]. This approach is often known-as carbon capture and utilization (CCU).…”

“…-(8) are solved simultaneously to compute the amount of CO and H 2 in the NSoR. The value of 'a' is then varied from 1 to 3 with approximately 10% increment while the DNI input to the SoR is set…”