2019
DOI: 10.3390/pr7100656
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Method of Moments Applied to Most-Likely High-Temperature Free-Radical Polymerization Reactions

Abstract: Many widely-used polymers are made via free-radical polymerization. Mathematical models of polymerization reactors have many applications such as reactor design, operation, and intensification. The method of moments has been utilized extensively for many decades to derive rate equations needed to predict polymer bulk properties. In this article, for a comprehensive list consisting of more than 40 different reactions that are most likely to occur in high-temperature free-radical homopolymerization, moment rate … Show more

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Cited by 11 publications
(5 citation statements)
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“…Given the set of acrylate polymerization reactions in Table and the method of moments rate equations in ref , we derived ordinary differential equations that describe the dynamics of the batch mini-reactors.…”
Section: Resultsmentioning
confidence: 99%
“…Given the set of acrylate polymerization reactions in Table and the method of moments rate equations in ref , we derived ordinary differential equations that describe the dynamics of the batch mini-reactors.…”
Section: Resultsmentioning
confidence: 99%
“…Moment equations 49,73,74 are used for closure and are useful since they provide a significant simplification in the set of model equations and make the simulations easier. The set of differential Equations ( 1)-( 7) mentioned above are simplified using moment equations which result in finite dimension summation terms and reduced complexity.…”
Section: Model Equations In Terms Of Momentsmentioning
confidence: 99%
“…Performing radical polymerizations at higher temperatures is attractive for technical applications because of high reaction rates, lower viscosities, and the access to polymers with lower molar masses . However, under these conditions, elemental reactions start to play a role that are negligible at lower temperatures. , Examples are the self-initiation of monomer and β scission of the macroradical, the latter reaction resulting in the formation of macromonomers and its elemental reactions. Because of the self-initiation process, the initiation kinetics is very sensitive to changes in the monomer concentration. , …”
Section: Introductionmentioning
confidence: 99%