Methods for the analysis, interpretation, and prediction of single-molecule junction conductance behaviour

Gorenskaia, Elena; Low, Paul J.

doi:10.1039/d4sc00488d

Chem. Sci.

2024

DOI: 10.1039/d4sc00488d

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Methods for the analysis, interpretation, and prediction of single-molecule junction conductance behaviour

Elena Gorenskaia,

Paul J. Low

Abstract: This article offers a broad overview of measurement methods in the field of molecular electronics, with a particular focus on the most common single-molecule junction fabrication techniques, the challenges in...

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Molecular Break Junction: A Stage for Redox Transformations

Neogi,

Sebastian

et al. 2024

Eur J Org Chem

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An exceptionally brilliant strategy to miniaturize electronic devices is to employ a single‐molecule between two electrodes for carrier conduction at single‐molecule break junctions (SMBJ). To understand the intrinsic mechanisms of operation at these junctions, extremely crucial is to study physical, chemical, and electrochemical properties employing single‐molecules at SMBJs. Further, redox‐based transformations at the nano‐junction could be achieved electrochemically to allow efficient switching between different redox states of a single‐molecule, showcasing the possibility of maneuvering transport properties with on‐off states of the molecule. Herein, are presented the fundamentals of SMBJs, and the electrochemically influenced transformations or switching of organic molecules pursued at SMBJs. Such an understanding of electrochemical phenomena at the nanoscale dimension could bridge the knowledge gap between macroscopic electronic circuits and single‐molecule electronic circuits, whereby the feasibility of switching between the states could maneuver the electronic properties as well as other photophysical parameters.

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Molecular Break Junction: A Stage for Redox Transformations

Neogi,

Sebastian

et al. 2024

Eur J Org Chem

View full text Add to dashboard Cite

show abstract

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Methods for the analysis, interpretation, and prediction of single-molecule junction conductance behaviour

Abstract: This article offers a broad overview of measurement methods in the field of molecular electronics, with a particular focus on the most common single-molecule junction fabrication techniques, the challenges in...

Cited by 1 publication

References 201 publications

Molecular Break Junction: A Stage for Redox Transformations

Molecular Break Junction: A Stage for Redox Transformations

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