Methods to Investigate Mechanisms of Electroorganic Reactions

Abstract

The sections in this article are Introduction Scope: Methods of Molecular Electrochemistry Historical Development Why and How to Investigate Mechanisms of Electroorganic Reactions Steps of Electrode Reaction Mechanisms General Transport Electron Transfer Chemical Kinetic Steps Adsorption Organic Electrode Reaction Mechanisms Electron Transfer Initiates Chemistry Nomenclature of Electrode Reaction Mechanisms Formal Description of Events at an Electrode Current‐Potential‐Time Relationships Concentration Profiles Methods of Mechanistic Electroorganic Chemistry Classification Controlled‐Potential Techniques Controlled‐Current Techniques Hydrodynamic Voltammetry Exhaustive Electrolysis Techniques How to Gain Access to Kinetics, Thermodynamics, and Mechanisms of Electroorganic Reactions Qualitative and Quantitative Investigation of Electrode Reaction Mechanisms General Recommendations for Mechanistic Analysis Some Mechanistic Examples Pure ET Reactions Follow‐up Reactions Preequilibria to ETs Catalytic Reactions How to Gain Additional Information about Electroorganic Reaction Mechanisms Simulation Ultramicroelectrodes Electrogravimetry Spectroelectrochemistry Conclusion Acknowledgment

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