2020
DOI: 10.26434/chemrxiv.12834125
|View full text |Cite
Preprint
|
Sign up to set email alerts
|

Methyl Radical Initiated Kharasch and Related Reactions

Abstract: An improved procedure to run halogen atom and related chalcogen group transfer radical additions is reported. The procedure relies on the thermal decomposition of di-<i>tert</i>-butylhyponitrite (DTBHN), a safer alternative to the explosive diacetyl peroxide, to produce highly reactive methyl radicals that can initiate the chain process. This mode of initiation generates byproducts that are either gaseous (N<sub>2</sub>) or volatile (acetone and methyl halide) thereby facilitating great… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 60 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?