Operational interpretations of quantum resource measures lie at the heart of quantum information processing technologies. In this paper, we show that the bipartite quantum correlation in terms of Wigner-Yanase skew information, is the minimal failure probability of a particular state ensemble discrimination task via associated least square measurement. We then derive a general relation between quantum coherence with respect to quantum operation and discriminating probability specific to least square measurement. Furthermore, we provide a wave-particle duality relation between bipartite quantum correlation and which-path information.