Mg-Doped ZnO-PVDF Composite Membranes by Interfacial Film-Forming Method for Adsorption and Piezoelectric Degradation of Tetracycline in Water

Cai, Zhihan; Xia, Wangzhe; Li, Haibo; Qin, Rui; Wu, Fangping; Wu, Jianhong; Yin, Xianze; Li, Zehao; Yang, Yongsheng

doi:10.1021/acsapm.4c01017

ACS Appl. Polym. Mater.

2024

DOI: 10.1021/acsapm.4c01017

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Mg-Doped ZnO-PVDF Composite Membranes by Interfacial Film-Forming Method for Adsorption and Piezoelectric Degradation of Tetracycline in Water

Zhihan Cai,

Wangzhe Xia,

Haibo Li

et al.

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Cited by 2 publications

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Organic–Inorganic Hybrid Perovskite for Ferroelectric Catalysis

Hu,

Jing,

Pan

et al. 2024

Advanced Materials

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Organic–inorganic hybrid perovskite ferroelectric has gained significant attention for its structural flexibility and diversity. They can directly utilize metal nodes and organic groups as active sites in catalysis. Additionally, their ferroelectric polarization occurs around these active sites, significantly enhancing catalytic activity and demonstrating immense potential for applications. However, their catalytic applications remain underexplored. This work marks the first utilization of the molecular perovskite ferroelectric [3,3‐difluorocyclobutylammonium]2CuCl4 (Cu‐DFCBA) as a catalyst for alkane oxidation. Under ultrasonic stimulation, it achieved a remarkable turnover number as high as 2402. Compared to inorganic ferroelectrics like lithium niobate (LiNbO3), the molecular ferroelectric exhibited a 1200‐fold increase in catalytic activity. This highlights Cu‐DFCBA's robust ferroelectric properties and underscores the vast potential of molecular ferroelectrics in catalysis, guiding future system designs.

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Organic–Inorganic Hybrid Perovskite for Ferroelectric Catalysis

Hu,

Jing,

Pan

et al. 2024

Advanced Materials

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Single‐Component White Emissive Organic–Inorganic Hybrid Copper Halide Composite Films for Remote UV‐pumped White Light‐Emitting Diodes with High Color Rendering Index

Liu,

Xie

et al. 2024

Advanced Optical Materials

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Lead‐free organic–inorganic metal halides (OIMHs) are highly desirable owing to their remarkable properties including low toxicity, structural diversity, high stability, and solution processability. Nevertheless, the development of their single‐component white emissive films remains a formidable challenge for remote white light‐emitting diodes (WLEDs) application. In this work, (C16H36N)2Cu2I4/polyvinylidene fluoride (PVDF) white emissive composite film is successfully fabricated through an in situ solvent evaporation crystallization process at room temperature. The elemental analysis and bonding between (C16H36N)2Cu2I4 and PVDF are demonstrated by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) measurements. In addition, this composite film exhibits a broadband white emission with two peaks. Notably, the best photoluminescence quantum yields (PLQYs) of the PVDF based composite film reaches an impressive 96.7%. A (C16H36N)2Cu2I4/PVDF based remote UV‐pumped WLEDs with an impressive color rendering index of 95.5 is realized. Finally, the in situ fabrication method is expanded to fabricate (C16H36N)2Cu2I4/polyacrylonitrile (PAN) composite films, and we further realized their single component remote WLEDs.

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Mg-Doped ZnO-PVDF Composite Membranes by Interfacial Film-Forming Method for Adsorption and Piezoelectric Degradation of Tetracycline in Water

Cited by 2 publications

References 61 publications

Organic–Inorganic Hybrid Perovskite for Ferroelectric Catalysis

Organic–Inorganic Hybrid Perovskite for Ferroelectric Catalysis

Single‐Component White Emissive Organic–Inorganic Hybrid Copper Halide Composite Films for Remote UV‐pumped White Light‐Emitting Diodes with High Color Rendering Index

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