Nanoparticles of
plasmonic materials can sustain oscillations of
their free electron density, called localized surface plasmon resonances
(LSPRs), giving them a broad range of potential applications. Mg is
an earth-abundant plasmonic material attracting growing attention
owing to its ability to sustain LSPRs across the ultraviolet, visible,
and near-infrared wavelength range. Tuning the LSPR frequency of plasmonic
nanoparticles requires precise control over their size and shape;
for Mg, this control has previously been achieved using top-down fabrication
or gas-phase methods, but these are slow and expensive. Here, we systematically
probe the effects of reaction parameters on the nucleation and growth
of Mg nanoparticles using a facile and inexpensive colloidal synthesis.
Small NPs of 80 nm were synthesized using a low reaction time of 1
min and ∼100 nm NPs were synthesized by decreasing the overall
reaction concentration, replacing the naphthalene electron carrier
with biphenyl or using metal salt additives of FeCl
3
or
NiCl
2
at longer reaction times of 17 h. Intermediate sizes
up to 400 nm were further selected via the overall reaction concentration
or using other metal salt additives with different reduction potentials.
Significantly larger particles of over a micrometer were produced
by reducing the reaction temperature and, thus, the nucleation rate.
We showed that increasing the solvent coordination reduced Mg NP sizes,
while scaling up the reaction reduced the mixing efficiency and produced
larger NPs. Surprisingly, varying the relative amounts of Mg precursor
and electron carrier had little impact on the final NP sizes. These
results pave the way for the large-scale use of Mg as a low-cost and
sustainable plasmonic material.