The natural-convection magnetohydrodynamic (MHD) flow usually takes place in the process of many industries, such as astrophysics and electronics. In this work, the MHD flow characteristic and heat behavior about the generalized Maxwell fluid passing the canted porous plate under the titled magnetic field is investigated, which is stemmed from the effect of the heat absorption, thermal radiation, the first-order chemical reaction and radiation absorption. And for the temperature and concentration, we established the single-phase-lag model to describe the anomalous transported process. By utilizing the Laplace-transform (L-T) and Fourier-sine transform (F-ST), the solutions in the transformed domain about velocity, temperature, concentration are given analytically. Then the semi-analytical solution can be denoted via the inverse F-ST and numerical inverse L-T. Further, the cognate parameters’ impacts on the solution are discussed and the results are displayed intuitively via profiles.