Methods to extend the spectral tuning range and signal-to-noise ratio via waveform optimization were examined using diplexed RF-modulation with continuous-wave distributed-feedback lasers, with relevance to MHz-rate laser absorption spectroscopy. With a bias-tee circuit, laser chirp rates are shown to increase by modulating the AC input voltage using square waves instead of sine waves and by scanning the laser below the lasing threshold. The effect of square waveform duty cycle and leading edge ramp rate are examined. Scan depths on the order of 1 cm −1 at a rate of 1 MHz are achieved with continuous-wave DFB quantum cascade lasers. The attenuation of the high-frequency laser signals due to detector bandwidth are also examined, and limitations are noted. Based on common detection system limitations, an optimization approach is established for a given detection bandwidth, with a representative optimized waveform determined for a 200 MHz system. This waveform is validated for accuracy across the scan range and for scan-to-scan repeatability using room temperature laser absorption measurements. The method is then deployed in a detonation tube to measure temperature, pressure, and CO concentration at MHz rates.