Micellar Binding of Phenoxide Ions to Cetyltrimethylammonium Chloride (CTAC)

Luminescence quenching of tris(2,2′-bipyridine)ruthenium(II) by 2,6-dimethylphenol and 4-bromo-2,6-dimethylphenol in sol–gel-processed silicate thin films

“…These compounds are present in commercial pesticide formulations and therefore constitute an important component in waste waters. In previous works, we studied the interaction between the complex ion tris(2,2 -bipyridine)ruthenium(II) (Ru(bpy) 2+ 3 ) and phenols as luminescence quenchers in homogeneous, microheterogeneous, and heterogeneous media [2][3][4][5][6][7].…”

Micellar Binding of α-Diimine–Chromium(III) Complexes (Cr(NN)3+3) to Sodium Dodecyl Sulfate (SDS)

“…Previous papers (2)(3)(4)(5) have dealt with the photophysics and mechanistic aspects of polypyridine complexes of transition metals in the presence of phenols. We also studied the interaction between the tris(2,2Ј-bipyridine)ruthenium(II) (Ru(bpy) 3 2ϩ ) excited state and phenols as luminescence quenchers in cationic micelles of cetyltrimethylammonium chloride (CTAC) (6) or anionic micelles of sodium dodecyl sulfate (SDS) (7). The binding or association constant of the phenols to the micelles was determined in each system.…”

Spectrophotometric determination of anionic micellar binding constants of ionized and non-ionized phenyl and methyl salicylates

“…The reported value of the cmc' of 0.008 m~l d m -~ was used in the calculation of fMs-and KsTp using equation (3). The values of cmc at different [NaOH], were also calculated using an iterative technique described elsewhere.…”

“…The luminescence quenching of tris (2,2' -bipyridine)ruthenium(II) dichloride has been used to measure the concentration of a few anionic polychlorophenols in the intermicellar aqueous pseudo-phase. 3 The results in these were interpreted in terms of binding to a single class of independent binding sites.…”