Benzeno, tolueno, etilbenzeno, m+p+o-xileno (BTEX) e dois trimetilbenzenos (BTEXT) foram monitorados no centro da cidade do Rio de Janeiro durante os anos de 2004 e 2005. Alguns poluentes legislados e parâmetros meteorológicos também foram monitorados, objetivando-se a análise da correlação entre esses dados. 94 amostras foram coletadas, usando cartuchos de carvão ativo, entre 9:00 e 15:00 h. Os valores médios de concentração obtidos foram: 14,5; 22,8; 9,19; 19,3; 8,5; 10,4 e 12,1 μg m -3 para benzeno, tolueno, etilbenzeno, m+p-xileno, o-xileno, 1,2,3-trimetilbenzeno e 1,3,5-trimetilbenzeno, respectivamente. Esses valores são similares às concentrações médias obtidas em outras cidades brasileiras, tais como, Porto Alegre, Volta Redonda e São Paulo, que usam o mesmo tipo de combustível. A análise multivariada mostrou que os BTEXT individuais são emitidos pelas mesmas fontes e não se correlacionam bem com os demais poluentes primários. Esses resultados podem ser atribuídos à contribuição das emissões evaporativas dos BTEXT e à formação de compostos orgânicos voláteis secundários na atmosfera.Benzene, toluene, ethylbenzene, m+p+o-xylene (BTEX) and two trimethylbenzenes (BTEXT) were monitored in Rio de Janeiro downtown area during 2004 and 2005. Some criteria pollutants and meteorological parameters were also determined in order to assess the main data correlations. 94 samples were collected, using activated charcoal cartridges, between 9:00 am and 3:00 pm. The mean concentrations obtained were: 14. 5, 22.8, 9.19, 19.3, 8.5, 10.4 and 12.1 μg m -3 for benzene, toluene, ethylbenzene, m+p-xylene, o-xylene, 1,2,3-trimethylbenzene and 1,3,5-trimethylbenzene, respectively. These values are similar to mean concentrations obtained in the Brazilian cities of Porto Alegre, Volta Redonda and São Paulo, which use the same type of fuel. Multivariate analyses showed that individual BTEXT are emitted by the same source and are not well correlated with other primary pollutants. These results may be due to the contribution of evaporative losses of the BTEXT and to the formation of secondary volatile organic compounds in the atmosphere.
Keywords: air pollution monitoring, hydrocarbons emision, BTEX, Rio de Janeiro
IntroductionMonoaromatic hydrocarbons are present in a considerable fraction of fossil fuels as gasoline and diesel. They can be emitted to the urban atmosphere either by volatilization or by incomplete combustion. Among these compounds, benzene has a direct impact on human health as a consequence of its carcinogenic and mutagenic properties.1 They are found mainly in the gaseous phase and have a considerable influence in the tropospheric chemistry, mainly in the formation of photochemical oxidants, as ozone and peroxyacetyl nitrate and in a minor extent, in the reaction with ozone. Among the aromatic compounds, benzene is the most harmful pollutant and it is responsible for myeloid leukemia. A World Health Organization (WHO) study 1 estimated that for an exposure to urban concentrations of 1.7 μg m -3 , 10 cases of leukemi...