The slope effect on flow erosivity and soil erosion still remains a controversial issue. This theoretical framework explained and quantified the direct slope effect by coupling the modified Green‐Ampt equation accounting for slope effect on infiltration, 1‐D kinematic wave overland flow routing model, and WEPP soil erosion model. The flow velocity, runoff rate, shear stress, interrill, and rill erosion were calculated on 0°–60° isotropic slopes with equal horizontal projective length. The results show that, for short‐duration rainfall events, the flow erosivity and erosion amounts exhibit a bell‐shaped trend which first increase with slope gradient, and then decrease after a critical slope angle. The critical slope angles increase significantly or even vanish with increasing rainfall duration but are nearly independent of the slope projective length. The soil critical shear stress, rainfall intensity, and temporal patterns have great influences on the slope effect trend, while the other soil erosion parameters, soil type, hydraulic conductivity, and antecedent soil moisture have minor impacts. Neglecting the slope effect on infiltration would generate smaller erosion and reduce critical slope angles. The relative slope effect on soil erosion in physically based model WEPP was compared to those in the empirical models USLE and RUSLE. The trends of relative slope effect were found quite different, but the difference may diminish with increasing rainfall duration. Finally, relatively smaller critical slope angles could be obtained with the equal slope length and the range of variation provides a possible explanation for the different critical slope angles reported in previous studies.