Microdetermination of phosphine by gas-liquid chromatography with microcoulometric, thermionic, and flame photometric detection

Berck, Ben; Westlake, W. E.; Günther, F. A.

doi:10.1021/jf60167a014

Cited by 31 publications

(13 citation statements)

References 14 publications

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“…Berck et al 93 presented the detection of PH 3 , in foodstuffs, air, and water, by gas-liquid chromatography with detectors of microcoulometric (MCD), thermionic (TD), and flame photometric (FPD) in the phosphorus mode. Generation of PH 3 was operated by addition of water to powdered phostoxin in a syringe followed by transferring into a flat bottom boiling flask for concentrating the PH 3 gas.…”

Section: Gas Chromatography-based Methodsmentioning

confidence: 99%

“…Regarding the important role of TD and FPD in the analysis of PH 3 , it is necessary to be mentioned that higher sensitivity, low background interference, stable baseline, and also the rapid and highly reproducible PH 3 elution from a short column can be obtained by an FPD. 93 Moreover, owing to the rapid oxidization and metabolization of PH 3 in biological samples (such as urine), the molecular form of PH 3 can be undetectable. The absorption of PH 3 can rapidly happen through the lungs followed by mostly exhalation of PH 3 through respiration.…”

Section: Critical Notementioning

confidence: 99%

“…Berck et al 93 . presented the detection of PH 3 , in foodstuffs, air, and water, by gas–liquid chromatography with detectors of microcoulometric (MCD), thermionic (TD), and flame photometric (FPD) in the phosphorus mode.…”

Section: Diagnosis and Detection Of Metal Phosphidesmentioning

confidence: 99%

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Development of detection methods for the diagnosis and analysis of highly toxic metal phosphides: A comprehensive and critical review

Mohammadinejad

Rizi

Oskuee

et al. 2021

Biotech and App Biochem

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Metal phosphides, especially aluminum phosphide, and phosphine (PH 3 ) are widely used as insecticides and rodenticides for protection of grains during process of storage and transportation. The main reason of poisoning with this compound is related to the conscious ingestion of salts or accidental inhalation of PH 3 . So the early and accurate diagnosis of poisoning can significantly help to the effective clinical treatment or recognition of death cause. PH 3 is somewhat unstable due to reaction with oxygen or hemoglobin leading to formation of oxy-acids phosphorous. Here, we critically reviewed the literature introducing the quantitative and qualitative methods for the detection of metal phosphides, PH 3 , and its products. This study obviously demonstrates that during past years, different diagnosis methods have been remarkably progressed. Head-space gas chromatography and confirmatory colorimetric methods have been as the most popular techniques. Also, the gas sensors are a promising method that must be more progressed.

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Section: Gas Chromatography-based Methodsmentioning

confidence: 99%

Section: Critical Notementioning

confidence: 99%

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Development of detection methods for the diagnosis and analysis of highly toxic metal phosphides: A comprehensive and critical review

Mohammadinejad

Rizi

Oskuee

et al. 2021

Biotech and App Biochem

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“…The direct determination of phosphine gas is not treated in the descriptions of standard methods, but there are methods for or thophosphate to which phosphine can be converted. Berck et al [5] have described gas-liquid chromatography of phosphine at the ppb level; Guiochon and Pommier [6] describe the gas chromatographic separation of gaseous hydrides including phosphine; and Dumas (1964) [45] has described the determination of phosphine in air down to 0.5 ppm.…”

Section: Phosphine Determinationmentioning

confidence: 99%

Development of solid state samplers for work atmospheres

Greifer¹,

Cadoff²,

Wing³

et al. 1974

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A program is described for evaluating the efficiency of solid sorbers for collecting trace quantities of hydrogen fluoride, phosphine, hydrogen cyanide, chlorine, and fluorine in work atmospheres for subsequent laboratory analysis. The gas handling and sampling instrumentation is described, and experimental results to date are presented. Sodium acetate is a very efficient sorber for hydrogen fluoride, and its solubility in water proves to be highly advantageous for subsequent HF determination by ion selective electrode. Potassium permanganate impregnated silica gel sorbs phosphine effectively, and Ascarite has been found to sorb hydrogen cyanide, but quantitative experiments on the latter two systems are still in progress. Work on chlorine and fluorine systems will be initiated in the near future. 1.

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“…This reaction forms an egg-yolk yellow product with a maximum absorption at 400 nm (Rangaswamy 1984). A gas chromatography (GC) method was applied for the analysis of PH 3 in the 1970s (Berck et al 1970). The most widely used phosphides, aluminum phosphide and magnesium phosphide, do not entirely decompose, and they leave residues that can be converted by acid hydrolysis to PH 3 in food commodities (Bruce et al 1962;Nowicki 1978;Banks 1986;Calzolai 1990).…”

mentioning

confidence: 99%

Residue Dynamics Studies of Aluminum Phosphide and Magnesium Phosphide in Stored Rice Utilizing a Sulfuric Acid‐Toluene Extraction Coupled with Gas Chromatography Analysis

et al. 2011

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Cereal Chem. 88(5):441-444A method for determination of aluminum phosphide and magnesium phosphide residues in rice was developed and validated. This work, through good laboratory practices, demonstrated aluminum and magnesium phosphide residue dynamics in stored rice. Rice samples were treated with sulfuric acid, which hydrolyzed phosphides to phosphine (PH 3 ), which was simultaneously trapped in toluene. The organic layer was filtered and then analyzed by gas chromatography with a flame photometric detector. The PH 3 calibration curves showed a strong linear relationship in the range of 0.012-1.2 mg/L, with a correlation coefficient of 0.999. The limit of detection of this method was 0.004 mg/kg. The average recoveries from samples fortified with aluminum phosphide and magnesium phosphide ranged from 76.8 to 106.5% with relative standard deviations below 10.2% (n = 5). PH 3 was applied separately to rice samples to study dissipation dynamics at application dosages of 9.0 and 12 g/m 3 , respectively. The results showed half-lives of aluminum and magnesium phosphide in rice to be 1.84 and 1.53 days, respectively. PH 3 was applied once at low and high dosages. The low dosage was 4.5 g/m 3 of aluminum phosphide and 6.0 g/m 3 of magnesium phosphide, and the high dosage was 9.0 and 12 g/m 3 for these two formulations, respectively. The final PH 3 residues were below 0.013 mg/kg (limit of quantification).

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Microdetermination of phosphine by gas-liquid chromatography with microcoulometric, thermionic, and flame photometric detection

Cited by 31 publications

References 14 publications

Development of detection methods for the diagnosis and analysis of highly toxic metal phosphides: A comprehensive and critical review

Development of detection methods for the diagnosis and analysis of highly toxic metal phosphides: A comprehensive and critical review

Development of solid state samplers for work atmospheres

Residue Dynamics Studies of Aluminum Phosphide and Magnesium Phosphide in Stored Rice Utilizing a Sulfuric Acid‐Toluene Extraction Coupled with Gas Chromatography Analysis

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