Microextrusion Printing of Multilayer Hierarchically Organized Planar Nanostructures Based on NiO, (CeO2)0.8(Sm2O3)0.2 and La0.6Sr0.4Co0.2Fe0.8O3−δ

Simonenko, Tatiana L.; Симоненко, Н. П.; Gorobtsov, Philipp Yu.; Simonenko, Elizaveta P.; Кузнецов, Н. Т.

doi:10.3390/mi14010003

Cited by 6 publications

(2 citation statements)

References 57 publications

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“…Previous research by various authors has shown the high efficiency of using printing technology to create miniaturized components and devices for alternative energy, electronics, and gas sensing. In particular, it has been demonstrated that approaches such as ink-jet printing [36][37][38][39], aerosol printing microplotter [40][41][42][43] and microextrusion [44][45][46][47][48][49] printing, and pen plottier printing [50][51][52] allow the use of inks of varied viscosity, forming coatings of different thickness and geometry with high accuracy and ensuring high reproducibility of microstructures and functional characteristics of the resulting planar structures.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Printing Features of a Hierarchical Nanocomposite Based on Nickel–Cobalt LDH and Carbonate Hydroxide Hydrate as a Supercapacitor Electrode

et al. 2023

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The hydrothermal synthesis of a hierarchically organized nanocomposite based on nickel–cobalt carbonate hydroxide hydrate of composition M(CO3)0.5(OH)·0.11H2O (where M is Ni2+ and Co2+) and nickel–cobalt layered double hydroxides (NiCo-LDH) was studied. Using synchronous thermal analysis (TGA/DSC), it was determined that the material retained thermal stability up to 200 °C. The crystal structure of the powder and the set of functional groups in its composition were determined by X-ray diffraction analysis (XRD) and Fourier transform infrared spectroscopy (FTIR). The resulting hierarchically organized nanopowder was employed as a functional ink component for microplotter printing of an electrode film, which is an array of miniature planar structures with a diameter of about 140 μm, on the surface of a nickel-plated steel substrate. Using scanning electron microscopy (SEM), it was established that the main area of the electrode “pixels” represents a thin film of individual nanorods with periodic inclusions of larger hierarchically organized spherical formations. According to atomic force microscopy (AFM) data, the mean square roughness of the material surface was 28 nm. The electrochemical properties of the printed composite film were examined; in particular, the areal specific capacitance at different current densities was calculated, and the electrochemical kinetics of the material was studied by impedance spectroscopy. It was found that the electrode material under study exhibited relatively low Rs and Rct resistance, which indicates active ion transfer at the electrode/electrolyte interface.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Printing Features of a Hierarchical Nanocomposite Based on Nickel–Cobalt LDH and Carbonate Hydroxide Hydrate as a Supercapacitor Electrode

et al. 2023

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“…The method of inkjet printing using ceramic printing compositions is cost-effective, easily scalable, and allows precise control of the shape, size, and morphology of the printed object [20,22]. Microextrusion or robocasting has also been used for the 3D printing of a SOFC anode based on the NiO/YSZ ceramic composite [23][24][25]. In general, microextrusion has the same advantages as inkjet printing.…”

Section: Introductionmentioning

confidence: 99%

An Anode-Supported Solid Oxide Fuel Cell (SOFC) Half-Cell Fabricated by Hybrid 3D Inkjet Printing and Laser Treatment

et al. 2023

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A NiO-10YSZ/10YSZ half-cell for anode-supported solid oxide fuel cells (SOFCs) was fabricated using 3D inkjet printing and layer-by-layer laser treatment of printing compositions followed by thermal sintering by a co-firing method. The optimal granulometric composition and rheological characteristics of the printing compositions to fabricate the NiO-10YSZ (60:40 wt.%) anode support, NiO-10YSZ (40:60 wt.%) anode functional layer (AFL), and 10YSZ electrolyte were determined. Effects of the pore former and laser post-treatment on the morphology of the as-prepared anodes for the manufacture of SOFC anode supports were studied, and the optimum laser exposure for hybrid 3D printing was determined. A mechanism of influence of the exposure of laser post-treatment on the morphology of the NiO-10YSZ anode supports has been proposed. The mass content of 10YSZ and the number of layers were shown to affect the surface microstructure and the thickness of the thin-film electrolytes deposited on the surface of the anode supports. The hybrid inkjet 3D printing offers great opportunities as it allows a one-pot procedure to fabricate a NiO-10YSZ/10YSZ SOFC half-cell for SOFC anode supports.

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Microplotter Printing of Hierarchically Organized NiCo2O4 Films for Ethanol Gas Sensing

et al. 2023

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Using a combination of chemical coprecipitation and hydrothermal treatment of the resulting dispersed system, a hierarchically organized NiCo2O4 nanopowder was obtained, consisting of slightly elongated initial oxide nanoparticles self-organized into nanosheets about 10 nm thick, which in turn are combined into hierarchical cellular agglomerates of about 2 μm. Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), selected area electron diffraction (SAED) and high-resolution transmission electron microscopy (HR-TEM) allowed to confirm the formation of NiCo2O4 powder with the desired crystal structure via additional heat treatment of the intermediate product. Energy-dispersive X-ray spectroscopy (EDX) was used to confirm the target metal ratio, and the uniform distribution of the elements (Ni, Co and O) was shown by mapping. The resulting nanopowder was employed to prepare functional inks suitable for microplotter printing of the NiCo2O4 film. It was found that an oxide film morphology is fully inherited from the hierarchically organized oxide nanopowder used. Atomic force microscopy (AFM) revealed the film thickness (15 μm) and determined the maximum height difference of 500 nm over an area of 25 μm2. Kelvin probe force microscopy (KPFM) showed that the surface potential was shifted to the depths of the oxide film, and the work function value of the material surface was 4.54 eV, which is significantly lower compared to those reported in the literature. The electronic state of the elements in the NiCo2O4 film under study was analyzed by X-ray photoelectron spectroscopy (XPS). Chemosensor measurements showed that the printed receptor layer exhibited selectivity and high signal reproducibility for ethanol detection. As the relative humidity increases from 0 to 75%, the response value is reduced; however, the sensor response profile and signal-to-noise ratio remain without significant changes.

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Microextrusion Printing of Multilayer Hierarchically Organized Planar Nanostructures Based on NiO, (CeO2)0.8(Sm2O3)0.2 and La0.6Sr0.4Co0.2Fe0.8O3−δ

Cited by 6 publications

References 57 publications

Synthesis and Printing Features of a Hierarchical Nanocomposite Based on Nickel–Cobalt LDH and Carbonate Hydroxide Hydrate as a Supercapacitor Electrode

Synthesis and Printing Features of a Hierarchical Nanocomposite Based on Nickel–Cobalt LDH and Carbonate Hydroxide Hydrate as a Supercapacitor Electrode

An Anode-Supported Solid Oxide Fuel Cell (SOFC) Half-Cell Fabricated by Hybrid 3D Inkjet Printing and Laser Treatment

Microplotter Printing of Hierarchically Organized NiCo2O4 Films for Ethanol Gas Sensing

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