Microfabrication of Anode Functional Layer in SOFC by 3D Printer

Abstract

This work aims to increase the interface between anode and electrolyte in solid oxide fuel cells by controlling the 3D microstructure with a commercial ink-jet 3D printer. Anode and electrolyte inks suitable for use in a 3D printer were prepared by altering the viscosity and the droplet size. A porous anode structure that ensures a flow path for gases was achieved by addition of acrylic particles into the anode ink. A dense electrolyte structure that prevents leakage was created. The anode and electrolyte layers were produced as long, flat strips which were aligned in parallel to form sheets; these sheets were stacked orthogonally to complete the 3D microstructure called the ‘anode functional layer’. The anode functional layer was roughly 100 micrometers on a side with a thickness of 4 micrometers. The anode functional layer was inserted between the anode and electrolyte. The assembled solid oxide fuel cell showed high performance when tested at 600 °C with dry methane as the fuel source.

Significance of advanced porous configurations in enhancing solid oxide fuel cell performance: a comparative analysis between conventional porous anodes and state-of-the-art variants

“…While the study successfully demonstrated the ability to maintain uniform diameters, it became evident that ensuring uniformity in the height of these cylinders required a higher degree of precision and refinement. Similarly, Takahashi et al [41] employed a 3D printer to fabricate controlled microstructures for the anode of SOFCs, producing droplets with sizes of 50, 100, and 150 µm. Notably, the research revealed that the maximum power density of a SOFC equipped with a 3D-printed anode remained on par with that of a conventional SOFC.…”