Particulate matter
(PM) pollution is a significant burden on global
economies and public health. Most present air filters are heavy, bulky,
and nontransparent and typically have inevitable compromise between
removal efficiency and air permeability. We report a scalable strategy
to create ultralight, thin, rubbery, self-assembled nanoarchitectured
networks (nanonetworks) with high-efficiency and transparency (ULTRA
NET) as air filters using capacitive-like electronetting technology.
By controlling the ejection, deformation, and phase separation of
charged droplets from a Taylor cone, our approach allows continuously
welded two-dimensional nanonetworks (∼20 nm fiber diameter)
to assemble into filters on a large scale. The resulting ULTRA NET
filters exhibit integrated properties of desirable pore structure
yet maintaining strikingly low thickness (∼350 nm) and free-standing
capability, 99.98% removal efficiency, and <0.07% of atmosphere
pressure for PM0.3 filtration at ∼85.6% transmittance,
which enable them to serve as a multifunctional filter against PMs
either in rigid solid or in soft oil forms and even biohazard pathogens.
This work should serve as a source of inspiration for the design and
development of high-performance fibrous materials for various filtration
and separation applications.