Silica aerogels are
highly porous materials with unique
properties
such as high specific surface area, high thermal insulation, and high
open porosity. These characteristics make them attractive for several
applications in closed microfluidic channels such as BioMEMS, catalysis,
and thermal insulation. However, aerogel-filled microchannels have
not been reported in the literature yet because of the complexity
of creating a process that controls the integration, shrinkage, and
mechanical stability of these materials inside a closed channel. In
this work, a process is presented to integrate aerogels in microchannels
with reproducibility, mechanical stability, and no shrinkage. This
protocol is based on the filling of channels during the gelation,
which is crucial to avoid shrinkage, CO2 supercritical
drying, and mechanical additives (polyethylene glycol and carbon nanotubes).
Furthermore, the influence of polyethylene glycol and carbon nanotubes
on the compressive strength, porosity, and specific surface area is
investigated. Following the suggested process protocol, the integration
of different aerogel compositions (with and without reinforcement)
is successfully achieved in the microchannels without shrinkage and
cracks. This research opens up new possibilities for the use of different
aerogels in microfluidics with structural integrity and enhanced functionality.