Abstract. A SO, sensor based on Na-I3-A120~ interfaced with an auxiliary electrode of Na2SO 4 formed in-situ and a solid mixture of Fe304, Fe2Os, 3Na20"5FezO3 as the reference electrode was developed. The sensor displayed a good response to changes in the partial pressure of SOt with a linear relationship between the measured emf and the logarithmic values of the partial pressure of SO2, as predicted by the Nernstian equation. Using an electron probe X-ray microanalyser, the formation of a Na2SO 4 reaction layer was confirmed on the surface of Na-~-A1203 tube due to surface reaction with the SO2 gas.