Marine microplastic (MP) pollution has aroused growing
public concern.
Reliable analytical techniques are required to assess the extent of
MP pollution. However, the detection of MPs is hindered by the challenge
of separating them from complex environmental substrates. Herein,
a simple and quick method to collect MPs from flowing seawater was
proposed using a two-phase (tributyl phosphate (TBP)–water)
system. The method can be used to efficiently and continuously separate
multiple sizes of MPs at different depths. Due to the hydrophobicity
of MPs, most of them would be collected at the two-phase interface.
At the same time, due to the formation of MP–oil aggregates
and the effect of buoyancy, very few MP–oil aggregates that
enter the water phase return to the two-phase interface. Results from
laboratory experiments revealed that the average recovery rate of
the seven types of MPs (polypropylene, polyethylene terephthalate,
polyvinyl chloride, polyamide 66, polycarbonate, polystyrene, and
polyethylene) reached 95.67% ± 0.47%. Furthermore, this method
was successfully employed to collect MPs from different seawater depths
in Zhanjiang Bay, demonstrating its efficiency under real-world conditions.
This method offers a novel approach for efficiently collecting MPs
from flowing water with a high enrichment efficiency.