Microporous and macroporous materials state-of-the-art of the technologies in zeolitization of aluminosilicate bearing residues from mining and metallurgical industries: A comprehensive review

Azizi, Dariush; Ibsaine, Fatima; Dionne, Justine; Pasquier, Louis-César; Coudert, Lucie; Blais, Jean-François

doi:10.1016/j.micromeso.2021.111029

Cited by 23 publications

(22 citation statements)

References 242 publications

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“…Zeolites are the most representative microporous materials composed of alumina and silica tetrahedra with wide applications in catalysis (petrochemical industry, refining processes, fine chemical production) and in gas storage and separation. Also, due to their ability to select molecules by size and shape and ion exchange selectivity, zeolites have been employed in removing heavy metal (Zn 2+ , Cd 2+ , Pb 2+ , Cu 2+ ), radioactive contaminants (Cs + , Sr 2+ , U 4+ ), dyes (crystal violet, acid orange 8) and others toxic pollutants from wastewater [1,2].…”

Section: Introductionmentioning

confidence: 99%

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Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash

Fungaro

Bertolini

2023

J. Appl. Mat. Tech.

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Zeolitic material in powder form was prepared from fly ash by direct activation treatment. The resulted fly ash-based zeolite was pelletizing and the effect of different inorganic (calcium hydroxide, bentonite, kaolinite) and organic (dextrin) binders with varying percentage was investigated. The zeolitic materials were analyzed by XRF, XRD, SEM, FTIR, TG-DTG and Nitrogen adsorption/desorption isotherm. Compression and impact tests have been used to study the deformation and breakage behaviour of spherical granules. The best performance was obtained by zeolite granular containing 5 wt.% bentonite and 5 wt.% kaolinite with mechanical strength and satisfactory water resistance. The synthesis of pelletized zeolite from by-products derived from coal combustion provides not only environmental and economic benefits, but also contributes to achieving the principles of sustainable development.

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Section: Introductionmentioning

confidence: 99%

“…Various methods for preparing synthetic zeolites are described in literature (Azizi et al, 2021;Ren et al, 2020;Zhang et al, 2022) [1,3,5]. One of the most common methods of obtaining zeolites from CCBs is the conventional hydrothermal synthesis, also known as, direct activation method.…”

Section: Introductionmentioning

confidence: 99%

Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash

Fungaro

Bertolini

2023

J. Appl. Mat. Tech.

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“…The production of zeolites from coal fly ash can be done by means of different hydrothermal activation methods [12][13][14]. The synthesis methods include direct hydrothermal, two-step hydrothermal, alkaline fusion-assisted hydrothermal, microwave-assisted methods, molten salt, solvent-free method, and ultrasonic-assisted method [15][16][17][18][19][20]. We focus on zeolitic materials because they possess a large surface area and a net negative charge which lead to a high adsorption capacity due to their channel structure, which allows them to easily attract heavy metals and cationic dyes.…”

Section: Introductionmentioning

confidence: 99%

“…We focus on zeolitic materials because they possess a large surface area and a net negative charge which lead to a high adsorption capacity due to their channel structure, which allows them to easily attract heavy metals and cationic dyes. Besides, they are more cost-effective due to the low cost and abundance of minerals that act as good cation exchangers [16,19].…”

Section: Introductionmentioning

confidence: 99%

The influence of separately and combined bentonite and kaolinite as binders for pelletization of NaA zeolite from coal fly ash

2022

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Pelletization of zeolitic materials is required to facilitate their practical industrial and commercial applications. Zeolite-NaA was synthesized from fly ash by the fusion method and shaped into spherical granules. Bentonite, kaolinite, and a combination of bentonite with kaolinite were tested as binders with different contents from 5 to 10 wt%. The pellet formation was optimized. The physicochemical properties of binders, zeolite powder, and zeolite granular were characterized by X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen adsorption/desorption isotherm, and scanning electron microscopy (SEM) among other techniques. Deformation and breakage behavior of spherical granulates by compression was also studied. The best performance was obtained by the pellet with 10% bentonite with satisfactory mechanical strength and water resistance. The XRD and SEM results revealed NaA zeolite granular with a typical cubic shape and high crystallinity formed on the surface of bentonite. This result presents a potential use of the coal fly ash to obtain pelletized NaA zeolite following the principles of circular economy and the sustainable development goals (SDGs), particularly SDG 12.

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“…Study on the synthesis mechanism of sodalite, gismondine, and zeolite-P1 zeolite materials from ladle furnace slag and fly ash Wenqing Ma 1 , Yuanrong Yi 1,2,3* , Minghang Fang 1 , Chunhui Li 1 , Jie Li 1 & Wei Liu 1 In this study, geopolymers were prepared using ladle furnace slag (LFS) and fly ash (FA), and hydrothermal treatment was then used to synthesize bulk zeolite molecular sieves with gismondine, zeolite-P1, and sodalite phases. The effect of the synthesis conditions on the crystalline phases of the zeolite molecular sieves was investigated by XRD.…”

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confidence: 99%

Study on the synthesis mechanism of sodalite, gismondine, and zeolite-P1 zeolite materials from ladle furnace slag and fly ash

Fang

et al. 2023

Sci Rep

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In this study, geopolymers were prepared using ladle furnace slag (LFS) and fly ash (FA), and hydrothermal treatment was then used to synthesize bulk zeolite molecular sieves with gismondine, zeolite-P1, and sodalite phases. The effect of the synthesis conditions on the crystalline phases of the zeolite molecular sieves was investigated by XRD. The results showed that the best zeolite molecular sieves were prepared with an LFS: FA ratio of 4: 6, a curing temperature of 40 °C, a curing time of 12 h, a sodium silicate modulus (Ms) of 1.4, a NaOH concentration of 4 mol/L, a hydrothermal temperature of 120 °C, and a hydrothermal time of 12 h. On this basis, the products were analyzed by SEM, N2 adsorption, and FT-IR. The results showed that the synthesized zeolite molecular sieves had mesoporous properties, and the degree of polymerization and cross-linking of the silica-aluminate gel were enhanced after hydrothermal treatment. In addition, the formation mechanism of the zeolite molecular sieves was explored through the changes of the silica-alumina during zeolite formation. This paper is the first to use the hydrothermal conversion of zeolite molecular sieves from LFS-FA based polymers to provide some guidance for the resource utilization of LFS and FA.

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Microporous and macroporous materials state-of-the-art of the technologies in zeolitization of aluminosilicate bearing residues from mining and metallurgical industries: A comprehensive review

Cited by 23 publications

References 242 publications

Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash

Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash

The influence of separately and combined bentonite and kaolinite as binders for pelletization of NaA zeolite from coal fly ash

Study on the synthesis mechanism of sodalite, gismondine, and zeolite-P1 zeolite materials from ladle furnace slag and fly ash

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