Microsolvation of aniline by argon: fluorescence excitation and two photon resonant ionization of An — Arn in a supersonic jet

Abstract

We report the results of a spectroscopic study of Aniline/Argon microclusters, A n -A r n with n = 1 to 11, which has been performed using a combination of the LIF and R2PI techniques.

Intermolecular vibronic spectroscopy of small Van Der Waals clusters: phenol- and aniline-(argon)2 complexes

“…Whereas, for large clusters (n> 3), broad features are generally observed [1][2][3]9], the spectra of the 1:2 complexes still exhibit vdW vibronic features. Whereas, for large clusters (n> 3), broad features are generally observed [1][2][3]9], the spectra of the 1:2 complexes still exhibit vdW vibronic features.…”

Absorption Spectroscopy, a Tool for Probing Local Structures and the Onset of Large-Amplitude Motions in Small KArn Clusters at Increasing Temperatures

“…One was to explore microsolvation by rare-gas atoms. For instance, the microsolvation of aromatic molecules was pioneered in the group of Leutwyler and further developed elsewhere. − The second motivation appeared in theoretical works, where the chromophore spectroscopy is proposed as a sensitive probe of the structure and phase (liquid or solid) of the rare-gas moiety that interacts with the chromophore. This point of view appeared in a series of works where the chromophore is a single alkali, − alkaline earth, , or boron atom.…”