Commercial 304 austenitic stainless steel was deformed at high temperatures. The experiments involved 2-hit hot compression and multi-pass hot torsion testing; the experimental variables included strain rate, temperature and interpass time. The relationship between these variables and the degree of interpass softening produced unexpected results. Specifically, the normal effect of temperature on the static softening kinetics was reversed at intermediate interpass times: the fractional softening decreased with increasing temperature for these times. The diffusion kinetics and segregation mechanics of the substitutional impurities in the material, combined with the experimental results, suggest that the temporary non-equilibrium segregation of phosphorus (and/or sulphur) to dislocations is responsible for the observed behaviour. Additionally, the observed trend in strain rate sensitivity with increasing deformation temperature indicates that dynamic strain aging was taking place.KEY WORDS: recrystallization; non-equilibrium segregation; stainless steel; static strain aging; dynamic strain aging.rate to vacancy concentration. It has been observed that, under specific thermal and straining conditions, the nonequilibrium segregation of substitutional solutes will occur in steel. 7) This involves the segregation of solute atoms to features such as grain boundaries in concentrations well in excess of equilibrium values. The non-equilibrium segregation is temporary; back diffusion from areas of excess concentration to adjacent regions of solute depletion will return the solute distribution to its equilibrium state given sufficient time. 8)
Materials and MethodsThe material used for virtually all the experiments in this work was a 304 austenitic stainless steel obtained from a single billet produced by Atlas Stainless Steel in Tracy, Quebec. In addition, a small amount of ultra-high purity 18Cr-12Ni-Fe 9,10) alloy was obtained and tested. The compositions of these steels are given in Table 1, along with the 304 specifications. Austenitic stainless steel has a low stacking fault energy, 11) in the range 21 mJ m Ϫ2 . Numerous studies of the recrystallization behaviour of such materials have been conducted over the past thirty years (especially involving torsion testing). [12][13][14] The stainless steel tested was obtained in the form of a billet 30-cmϫ15-cmϫ15-cm. The billets were sectioned parallel to the transverse direction and the sections sliced along the normal direction. After machining, the resulting cylindrical samples had their longitudinal axes parallel to the normal direction of the billet. The initial grain size was not a variable of interest in this work, but was essentially constant and in the range 80-100 mm. Torsion samples (Dϭ6.3 mm, Lϭ22 mm) were also machined from the same billet. These were machined such that the longitudinal axis of the samples were aligned along the rolling direction of the billet.Two-hit compression tests were performed primarily for the study of static softening. The tests were co...