Inks comprised of metallic Fe or Ni powders, an elastomeric binder, and graded volatility solvents are 3D-printed via syringe extrusion and sintered to form metallic cellular structures. Similar structures are created from Fe 2 O 3 and NiO particle-based inks, with an additional hydrogen reduction step before sintering. All sintered structures exhibit 92-98% relative density within their struts, with neither cracking nor visible warping despite extensive volumetric shrinkage (%70-80%) associated with reduction (for oxide powders) and sintering (for both metal and oxide powders). The cellular architectures, with overall relative densities of 32-49%, exhibit low stiffness (1-6 GPa, due to the particular architecture used), high strength (4-31 MPa), and high ductility, leading to excellent elastic and plastic energy absorption, when subjected to uniaxial compression.
IntroductionCellular materials exhibit numerous advantages over dense materials due to their high specific stiffness, strength, damping, energy absorption, and surface areas. [1][2][3][4] Both iron and nickel, pure or alloyed, have potential uses in cellular architectures for energy storage, [2,[5][6][7] emissions control, [2] catalyst supports, [1,8] and structural applications. [1,3,4,[8][9][10] The micro-architectures of ordered, periodic cellular materials such as scaffolds, honeycombs, lattices, and trusses can be optimized to provide additional improvement on these properties over randomly oriented cellular architectures. [8,[11][12][13] However, the widespread commercial and industrial adoption of cellular metal structures has been hindered by the fact that they are difficult and/or costly to manufacture at sufficient scales and rates relative to traditional metallic structures fabricated using long-established manufacturing methods such as casting. This is especially true for high-melting metals such as Fe and Ni which, unlike Al, are difficult to foam in the liquid state.We recently introduced a versatile and simple process for the additive manufacturing of cellular, metallic architectures, where a liquid ink, consisting of a suspension of metal oxide or metal particles, is first 3D-printed into a structure, and this structure is then subjected to sintering, with an intermediate thermochemical reduction step if oxides are used. [14] A similar direct ink writing approach has been used to produce reticulated sheets of TiH 2 that were then rolled or folded into scrolls or origami shapes [15,16] and Ti-6Al-4V scaffolds for bone implants. [17][18][19] Unlike established metal additive manufacturing methods (e.g., selective laser sintering or electron-beam sintering or melting [20] ), our extrusion-based method can be utilized to 3D-print complex architectures comprised of many layers from an extensive range of materials (e.g., ceramics, metals, biologics) with no required drying time and with a single 3D-printer at room temperature. [14,21] In our previous work, we 3D-printed, reduced,[*] Prof.