Microstructural Characterization of Shrouded Plasma-Sprayed Titanium Coatings

Abstract

Titanium and its alloys are often used for corrosion protection because they are able to offer high chemical resistance against various corrosive media. In this paper, shrouded plasma spray technology was applied to produce titanium coatings. A solid shroud with an external shrouding gas was used to plasma spray titanium powder feedstock with aim of reducing the oxide content in the as-sprayed coatings. The titanium coatings were assessed by optical microscope, scanning electron microscopy, X-ray diffraction, LECO combustion method and Vickers microhardness testing. The results showed that the presence of the shroud and the external shrouding gas led to a dense microstructure with a low porosity in the plasma-sprayed titanium coatings. The oxygen and nitrogen contents in the titanium coating were kept at a low level due to the shielding effect of the shroud attachment and the external shrouding gas. The dominant phase in the shrouded titanium coatings was mainly composed of α-Ti phase, which was very similar to the titanium feedstock powders. The shrouded plasma-sprayed titanium coatings had a Vickers microhardness of 404.2 ± 103.2 HV.

Effect of Shroud in Plasma Spraying on Chemical Composition and Thickness of Titanium Coatings

“…A SG-100 plasma gun from Praxair surface technologies, Indianapolis, IN, USA, together with a shroud attachment [24,25], was then used to plasma spray the pure titanium powder, as shown in Figure 2. The plasma gun with the shroud attachment was mounted on a 6-axis robot.…”

Fabrication of Titanium Coatings for Medical Device Applications

“…Plasma spray process has been used for several decades to deposit various coatings for different purposes such as thermal barrier, wear resistance and biocompatibility so on. Shrouded plasma spray modifies the spray torches by using a shroud attachment at the end of plasma gun [11][12]. The shroud could shield the plasma flame physically from the ambient air.…”